An approach to the simultaneous measurement of refractive-index (RI) and temperature changes using optical ring resonators is proposed and theoretically demonstrated. With a liquid-core silica ring resonator as an example, two different-order whispering gallery modes (WGMs) might differ in not only RI but also temperature sensitivities. Thus, a second-order sensing matrix should be defined based on these WGMs to determine RI and temperature changes simultaneously. The analysis shows that the RI and temperature detection limits can be achieved on the order of 10 −7 RI unit and 10 −3 K at a wavelength of approximately 780 nm.OCIS codes: 280.4788, 280.6780, 140.4780. doi: 10.3788/COL201210.052802. Optical microresonators of various shapes, such as microdisks [1] , microtoroids [2,3] , microspheres [4,5] , and microrings [6−10] , have been widely studied. In these resonators, light propagates in the form of whispering gallery modes (WGMs) because of its total internal reflection along the curved boundary between high and low refractive-index (RI) materials. Microresonators with WGMs are widely used as RI sensors for biological material detection [4,9] and chemical-concentrationchange measurements [5−8] , among others, because of the high Q factors and, thus, long light-material interaction paths. However, WGMs are also sensitive to thermal fluctuations induced by environmental temperature variations or probe-induced energy absorptions. In particular, for RI sensors with high Q factors, the resonance instability due to temperature-induced fluctuations significantly impairs sensor performance [11] . In such cases, temperature control devices, such as thermoelectric cooling units, are usually implemented to ensure small temperature fluctuations [12] . Another way of reducing resonance thermal drift is the introduction of some materials with negative thermal-optic coefficients in the cavity mode volume to compensate the positive thermal-optic coefficient of the ring resonator material [13−15] . However, this method requires precise control of the coating layer thickness [13,14] or resonator size [15] . In practice, achieving such precision, where the thermal drift can be eliminated, is difficult. Moreover, some nonuniformity of the coating layer or resonator further increases residual thermal drift. Meanwhile, the ultrasensitive shift of the WGM resonance to the ambient temperature can be used to design highly sensitive thermal sensors [16−18] , for which the bulk RI should be kept unchanged.This letter theoretically analyzes the use of optical ring resonators for the simultaneous measurement of RI and temperature changes. Both the RI and temperature sensitivities of the WGMs in a ring resonator are studied as a function of the ring wall thickness and WGM order. The results show that a ring resonator of any wall thickness has two WGMs of different orders with different RI and temperature sensitivities. By monitoring the resonant wavelength shifts of the WGMs of these two orders, a second-order sensing matrix can...