Temperature Dependence of Polymer Network Diffusion

Abstract

The swelling dynamics of polymer gels are characterized by the (collective) diffusion coefficient of the polymer network. Here, we measure the temperature dependence of the diffusion coefficients of polymer gels with controlled homogeneous network structures using dynamic light scattering. By developing the procedure for decomposing the diffusion coefficient into mixing and elastic contributions, we find that the elastic contribution is a linear function of the absolute temperature with a significant negative constant term. This feature is formally identical to the recently discovered "negative energy elasticity." Our findings further advance practical applications of polymer gels because the diffusion coefficient determines the swelling response time.