1999
DOI: 10.1103/physrevb.60.2579
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Temperature dependence of the electronic structure ofC60films adsorbed onSi(001)

Abstract: We report here the temperature-dependent measurements of the valence spectra, the C 1s and the Si 2p core level spectra of the one monolayer C 60 film adsorbed on Si͑001͒-(2ϫ1) and Si͑111͒-(7ϫ7) surfaces, using photoelectron spectroscopy. At 300 K, most C 60 molecules are physisorbed with the coexistence of minority chemisorbed species on both Si͑001͒-(2ϫ1) and Si͑111͒-(7ϫ7) surfaces. After annealing the samples at 670 K, C 60 molecules change the bonding nature to a chemisorption that has both covalent and io… Show more

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Cited by 51 publications
(43 citation statements)
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References 77 publications
(122 reference statements)
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“…Only after annealing the sample the majority of the molecules are found in the lower configuration. It is also worth noting here that some recent evidence supports a strong rearrangement of the Si(111) surface upon the adsorption of C 60 [17]. In these experiments, after annealing one monolayer of C 60 at 670 K, the (7×7) diffraction pattern is lost and a (1×1) pattern appears in its place.…”
mentioning
confidence: 79%
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“…Only after annealing the sample the majority of the molecules are found in the lower configuration. It is also worth noting here that some recent evidence supports a strong rearrangement of the Si(111) surface upon the adsorption of C 60 [17]. In these experiments, after annealing one monolayer of C 60 at 670 K, the (7×7) diffraction pattern is lost and a (1×1) pattern appears in its place.…”
mentioning
confidence: 79%
“…imental techniques, oscillate between 3±1 electrons [16], and ∼0.21 electrons [17]. The theoretical calculations might be important to understand this discrepancy.…”
mentioning
confidence: 99%
“…[19][20][21] The structure at 284.46 eV has been observed only in MBE experiments where the substrate temperature was at least 700 K; it is considered representative of the formation of several covalent Si-C bonds that will lead to cage opening and fragmentation at higher temperatures. The two peaks in the 283-284 eV range are representative of carbides showing different properties, in particular the component at 283.03 arise from amorphous and stoichiometric SiC 20,22 or from the cubic polytype, 23 while the one at 283.73 can be associated to non-stoichiometric SiC compounds 24,25 or to hexagonal polytype SiC. 26 Noteworthy, the presence of these two carbide-related peaks is a clear evidence that the SiC synthesis has been achieved at 300 K, while in MBE experiments this occurs at temperatures of 1000 K or higher.…”
Section: Experimental Findingsmentioning
confidence: 99%
“…[6][7][8][9][10] The lower temperature at which SWNT decomposition occurs at first appears anomalous-curvature of carbon nanotubes and associated bond strain is smaller than in fullerenes and, in the absence of defects, there are no fivemembered rings, suggesting that carbon nanotubes should be theoretically more stable. However, valence band photoemission spectra ͓Fig.…”
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confidence: 99%
“…[2][3][4] Moreover, knowledge of the temperature at which carbide formation occurs is necessary to determine the stability of silicon/carbon nanotube interfaces which would result from integration of carbon nanotubes with silicon-based electronics. Although much effort has been directed toward understanding the interaction and thermal decomposition of C 60 on Si͑111͒ surfaces, [5][6][7][8][9][10][11] a closely related system, the inability to evaporate carbon nanotubes makes exploring the interaction of these species with elemental surfaces difficult.…”
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confidence: 99%