2024
DOI: 10.1021/acs.jpca.4c04990
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Temperature-Dependent Kinetics of the Reactions of the Criegee Intermediate CH2OO with Aliphatic Aldehydes

Jonas J. Enders,
Zachary A. Cornwell,
Aaron W. Harrison
et al.

Abstract: Criegee intermediates, formed by alkene ozonolysis in the troposphere, can react with volatile organic compounds (VOCs). The temperature-dependent kinetics of the reactions between the Criegee intermediate CH 2 OO and three aliphatic aldehydes, RCHO where R = H, CH 3 , and C 2 H 5 (formaldehyde, acetaldehyde, and propionaldehyde, respectively), have been studied using a laser flash-photolysis transient absorption spectr… Show more

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