Minority electron mobilities in GaAs, In 0.53 Ga 0.47 As , and GaAs 0.50 Sb 0.50 calculated within an ensemble Monte Carlo model Monte Carlo is used to model the electric field and temperature dependence of the electron ionization coefficient, ␣, in In 0.53 Ga 0.47 As, using a two-component ionization rate to account for its observed anomalous dependence on the electric field. ␣ is predicted to decrease with temperature at fields above approximately 180 kV/cm, where impact ionization is limited by the high-energy electron population, and to increase with temperature at lower fields, where it is enhanced by the decreasing ionization threshold energy, in agreement with experimental observations.