In this study, we investigate the fabrication of ambient room temperature responsive shape memory polyurethane (SMPU)‐coated fabric using a simple dip coating method, aiming to enhance the shape memory response of smart textiles. Two SMPU were synthesized using different chain extender 1,4 butanediol (BDO‐SMPU) and polyethylenimine (PEI‐SMPU). Critical parameters such as SMPU concentration, dwell time, and coating solution temperature are optimized to ensure exceptional shape memory performance while also maintaining the fabric's handle, comfort, and durability. We determined that PEI‐SMPU/Cotton fabric exhibits superior memory performance, with a 90.2% shape recovery at a 1% PEI‐SMPU concentration. Conversely, BDO‐SMPU fabric demonstrated a 75.8% shape recovery under different conditions (10% SMPU concentration, 50°C solution temperature). Furthermore, shape recovery is influenced by programming temperature and load; at 35°C and 10 N load, PEI‐SMPU/Cotton significantly outperforms BDO‐SMPU/Cotton, showing about 20% improvement in shape recovery. This study indicates that modifying SMPU from BDO‐SMPU to PEI‐SMPU can notably enhance shape recovery performance at 35°C, marking a significant advancement in human body temperature responsive smart fabric technology.