2024
DOI: 10.1002/cjoc.202400947
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Temperature‐Driven Axial‐Equatorial Isomerism and Magnetic Relaxation on Low‐Spin Co(II) Borohydride Complexes

Jing‐Yu Wang,
Zhen Li,
Lu Zhang
et al.

Abstract: Comprehensive SummaryCrystalline materials with diastereomerism serve as ideal prototypes for investigating the influence of coordination environments on chemophysical properties. In this study, we synthesized a pair of axial‐equatorial isomers [Co(II)(HB(timtBu)3)(cis‐dppen)](BF4)·solv ([HB(timtBu)3]− = hydrotris(3‐tertbutyl‐2‐thioxoimidazol‐1‐yl)borate; cis‐dppen = cis‐1,2‐bis(diphenylphosphino)ethene; solv = 0.5THF·2H2O and 2H2O for ax‐CoHS2P2 and eq‐CoHS2P2, respectively), by varying the crystallization te… Show more

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