A series of measurements was conducted to characterize the structure of a 1 m diameter methanol pool fire steadily burning with a constant lip height in a well-ventilated quiescent environment. Time-averaged local measurements of gas-phase temperature were conducted using 50 μm diameter, Type S, bare wire, thermocouples with a bead that was approximately spherical with a diameter of about 150 μm. The thermocouple bead temperature was corrected for radiative loss and thermal inertia effects. The contribution of the radiative loss correction and thermal inertia correction terms to uncertainty of the gas velocity was analyzed. A simulation of the 1 m methanol pool fire was conducted using the Fire Dynamics Simulator (FDS) to obtain the gas velocity distribution above the burner which helped correct the thermocouple temperature measurement to obtain the gas temperature. The gas temperature distribution profile above the burner centerline was compared to previous studies of a 30 cm methanol fire. The maximum mean gas temperature was 1371 K, which occurred 30 cm above the burner on the centerline. Careful analysis determined that the average combined uncertainty of the mean and the standard deviation of the measured gas temperature was 5 % and 26 %, respectively. The actual heat release rate was measured using oxygen consumption calorimetry and compared favorably with the ideal heat release rate calculated from the measured mass burning rate. The heat flux distribution about the pool fire was measured using fourteen wide-angle view, water-cooled, Gardon-type, total heat flux gauges. The radiative emission from the fire was estimated by considering the radiative heat flux through a virtual cylinder about the fire and by a single point estimate. The radiative emission measurements coupled with the mass loss measurement allowed determination of the radiative fraction, which was equal to 0.22 ± 16 % and 0.20 ± 34 % for the multi-location and single-location measurements, respectively. Flame characteristics, such as, the mean flame height, pulsation frequency and the flame instability near the fuel surface, were analyzed using the 30 Hz video record of the fire. The mean flame height was measured as 1.10 m ± 0.22 m above the burner rim and the puffing frequency was about 1.37 Hz, which was consistent with a Fourier analysis of the transient thermocouple measurements (=1.39 Hz ± 0.013 Hz). The pool surface temperature was measured to be nearly the fuel boiling point.