The effect of annealing both in the oxygen atmosphere and at room temperatures on physical properties such as the pseudogap (Δ*(T)) and excess conductivity (σ′(T)) of untwined YBa
2
Cu
3
O
7−δ
(YBCO) single crystal with a small deviation from oxygen stoichiometry is studied. It was revealed that as the charge carrier density, n
f
, increases, Т
с
also slightly increases, whereas the temperature of the pseudogap opening, T*, decreases noticeably, which is consistent with the phase diagram (PD) of cuprates. The excess conductivity in the vicinity of T
c
is represented by the Aslamazov-Larkin and Hikami-Larkin fluctuation theories, illustrating the three-dimensional to two-dimensional (i.e. 3D-2D) crossover with an increase in temperature. The crossover temperature T
0
determines the coherence length along the
c
axis is ξ
c
(0) = 0.86 Å, that is 2.6 times larger than for optimally doped YBCO single crystals with defects. Taking into account the short coherence length in high-temperature superconductors, in the model of free charge carriers the phase relaxation time of fluctuating Cooper pairs is determined, τ
φ
(100 K) = (4.55 ± 0.4) · 10
−13
s, which is slightly (1.2 times) larger than in well-structured YBCO films, and as in films, does not depend on n
f
. It is shown that Δ*(T) at different annealing stages practically does not change its shape. As in the well-structured YBCO films, Δ*(T) demonstrates maximum at T
pair
~124 K which depends weakly on n
f
. However, the maximum value of Δ*(T
pair
) increases with increasing n
f
, as it follows from the PD of cuprates. Comparing the experimental data with the Peters-Bauer theory we estimated the density of local pairs ≈ 0.3 near T
c
that is a common value for high-temperature superconductors.