The efficiency of different fuels in combustion processes has been an ongoing quest. Temperature measurements and color spectrum of premixed combustion flames are the accepted parameters to study. This work's aim is to do so simultaneously, with a very simple setup and saving computational resources. This method does not ask to synchronize two sets of measurements, avoid the need for complicated setup alignments, and use a single digital camera. Instead, the temperature and color spectrum are measured simultaneously using digital laser speckle photography and an image processing approach. The recorded data for both measurements are acquired using only a color digital camera, where the red (r) color channel is used to record data for temperature measurements, and the blue (b) and green (g) color channels are utilized to record the flames' color spectrum. To calculate the flames' temperature field, the Abel inversion technique was carried out, while the image processing required crosstalk image correction, image segmentation, and image filtering. The crosstalk image correction is the main feature that establishes an unequivocal relationship between image color and color spectrum of flames. The technique was tested on flames produced with a liquefied petroleum gas fed torch using different equivalence ratios. The temperature values obtained with this method are in good agreement with those obtained with a thermocouple.