2020
DOI: 10.5702/massspectrometry.a0083
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Temperature-Resolved Proton Transfer Reactions of Biomolecular Ions

Abstract: Temperature-resolved proton transfer reactions of multiply-protonated angiotensin I, disul de-intact and-reduced lysozyme, and ubiquitin ions to primary, secondary and aromatic amines were examined in the gas phase. Absolute reaction rate constants for the proton transfer were determined from the intensities of the parent and product ions in mass spectra. Dramatic changes were observed in the distribution of product ions and the reaction rate constants. In particular, the rate constants for disul de-intact lys… Show more

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