Temperature‐responsive linear polyelectrolytes and hydrogels based on [2‐(methacryloyloxy)ethyl] trimethylammonium chloride and <i>N</i>‐isopropylacrylamide and their complex formation with potassium hexacyanoferrates (II, III)

Khutoryanskiy, Vitaliy V.; Nurkeeva, Zauresh S.; Mun, Grigoriy A.; Sergaziyev, Aibek D.; Kadłubowski, Sławomir; Fefelova, N. A.; Baizhumanova, T.S.; Rosiak, Janusz M.

doi:10.1002/polb.10693

Cited by 13 publications

(13 citation statements)

References 13 publications

Supporting

Mentioning

Contrasting

Order By: Relevance

“…Water‐soluble polymers exhibiting lower critical solution temperature (LCST) in water have attracted considerable attention in recent years. Numerous applications of these polymers in controlled release systems,1–3 biotechnology,4 separation and enrichment technologies,5 and stabilization of colloids6, 7 have stimulated researchers to develop new polymers and to optimize the properties of well‐known systems.…”

Section: Introductionmentioning

confidence: 99%

Novel temperature‐responsive water‐soluble copolymers based on 2‐hydroxyethylacrylate and vinyl butyl ether and their interactions with poly(carboxylic acids)

Mun

Nurkeeva²,

Akhmetkalieva³

et al. 2005

J Polym Sci B Polym Phys

View full text Add to dashboard Cite

Novel water-soluble amphiphilic copolymers have been synthesized by free radical copolymerization of 2-hydroxyethylacrylate with vinyl butyl ether. In water these copolymers exhibit lower critical solution temperature, which depends on the content of hydrophobic vinyl butyl ether units. The interaction between these copolymers and poly(acrylic acid) or poly(methacrylic acid) in aqueous solutions results in formation of interpolymer complexes stabilized by hydrogen bonds and hydrophobic interactions. An increase in hydrophobicity of the copolymers leads to the enhancement of their complex formation ability with respect to poly(acrylic acid) and poly(methacrylic acid). Poly-(methacrylic acid) forms stronger complexes with the copolymers when compared with poly(acrylic acid). The complexes exhibit dual sensitivity to pH-and temperature and this property may be easily adjusted regulating the strength of interaction. V V C 2005 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 44: 195-204, 2006

show abstract

Section: Introductionmentioning

confidence: 99%

Novel temperature‐responsive water‐soluble copolymers based on 2‐hydroxyethylacrylate and vinyl butyl ether and their interactions with poly(carboxylic acids)

Mun

Nurkeeva²,

Akhmetkalieva³

et al. 2005

J Polym Sci B Polym Phys

View full text Add to dashboard Cite

show abstract

“…The synthesis of the linear copolymers was performed by the γ‐radiation copolymerization of MADQUAT with NIPAAM in 10% aqueous solutions, as described in refs. 10 and11. The copolymerization was conducted in sealed glass ampules with an MRX‐γ‐25M setup equipped with a 60 Co source with a dose rate of 0.16 Gy/s.…”

Section: Methodsmentioning

confidence: 99%

Polyelectrolyte complexes of linear copolymers and hydrogels based on 2‐[(methacryloyloxy)ethyl]trimethylammonium chloride and N‐isopropylacrylamide

Mun¹,

Khutoryanskiy

Nurkeeva³

et al. 2004

J Polym Sci B Polym Phys

View full text Add to dashboard Cite

The formation of polyelectrolyte complexes of linear copolymers and hydrogels based on copolymers of 2-[(methacryloyloxy)ethyl]trimethylammonium chloride with N-isopropylacrylamide (MADQUAT-NIPAAM) and poly(acrylic acid) (PAA) has been studied. The composition of the copolymer has been found to affect the composition of the polyelectrolyte complexes significantly, and the molecular weight of PAA influences their aggregation stability. Hydrogels of MADQUAT-NIPAAM immersed in solutions of PAA undergo contraction because of the formation of gel-polymer complexes. The rate of contraction and the final swelling degree of the gel-polymer complexes depend on the concentration of PAA in solution and its molecular weight.

show abstract

“…In particular, water-soluble polymers exhibiting lower critical solution temperature (LCST) are among the most interesting stimuli-sensitive materials due to numerous potential applications in controlled release systems [1], biotechnology [2], separation and enrichment technologies [3], and stabilization of colloids [4]. Pursuing these applications requires precise control over the properties of stimuli-responsive materials.…”

Section: Introductionmentioning

confidence: 99%

New Thermo-Sensitive Hydrogel Based on Copolymer of 2-hydroxyethyl Acrylate and Ethyl Acrylate

Rakhmetullayeva

Azhkeyeva

Yeligbayeva

et al. 2017

Eurasian Chem. Tech. J.

View full text Add to dashboard Cite

In this work firstly the thermo-sensitive polymer hydrogels were obtained by three-dimensional radical copolymerization of water-soluble HEA and hydrophobic monomer ethyl acrylate (EA) in the presence of crosslinking agent N,N'-methylenebisacrylamide (BAA). The hydrogels with certain copolymer compositions showed thermo-sensitive behavior in aqueous solutions. The regularity of complex formation of cross-linked copolymer HEA-EA with anionic and cationic surface-active substances have been studied. The swelling behavior of the hydrogels in cetylpyridinium bromide aqueous solutions was studied. Increased swelling of the hydrogels was observed in the surfactant solutions. The increased swelling was more prominent for the hydrogels with a higher content of the hydrophobic moiety in the copolymer composition and with the higher surfactant concentration. The reason for the observed phenomenon is discussed.

show abstract

Temperature‐responsive linear polyelectrolytes and hydrogels based on [2‐(methacryloyloxy)ethyl] trimethylammonium chloride and N‐isopropylacrylamide and their complex formation with potassium hexacyanoferrates (II, III)

Cited by 13 publications

References 13 publications

Novel temperature‐responsive water‐soluble copolymers based on 2‐hydroxyethylacrylate and vinyl butyl ether and their interactions with poly(carboxylic acids)

Novel temperature‐responsive water‐soluble copolymers based on 2‐hydroxyethylacrylate and vinyl butyl ether and their interactions with poly(carboxylic acids)

Polyelectrolyte complexes of linear copolymers and hydrogels based on 2‐[(methacryloyloxy)ethyl]trimethylammonium chloride and N‐isopropylacrylamide

New Thermo-Sensitive Hydrogel Based on Copolymer of 2-hydroxyethyl Acrylate and Ethyl Acrylate

Contact Info

Product

Resources

About