Template‐Directed Synthesis of Pillared‐Porous Carbon Nanosheet Architectures: High‐Performance Electrode Materials for Supercapacitors

Fan, Zhuangjun; Liu, Yang; Yan, Jun; Gao, Ning; Wang, Qian; Wei, Tong; Zhi, Linjie; Wei, Fei

doi:10.1002/aenm.201100654

Cited by 277 publications

(181 citation statements)

References 32 publications

Supporting

Mentioning

175

Contrasting

Unclassified

Order By: Relevance

“…7a, the CV curves at scan rates from 5 mV s À1 to 200 mV s À1 demonstrate an almost quasi-rectangular shape without obvious distortion, indicating its ideal capacitive behavior and good reversibility. 39,40 Figure 7b shows the GCD curves of N-PCNs at the different current densities from 0.5 A g À1 to 10 A g À1 , which exhibit highly symmetrical isosceles triangular shapes at various current densities, suggesting an ideal EDLC behavior and superior electrochemical reversibility. The long-time cycling stability of the material is another important factor to identify the feasibility for practical application of supercapacitors.…”

Section: Resultsmentioning

confidence: 99%

Porous Carbon Nanosheets Prepared from Plastic Wastes for Supercapacitors

Wang

Liu

Zhang

et al. 2018

Journal of Elec Materi

View full text Add to dashboard Cite

Section: Resultsmentioning

confidence: 99%

Porous Carbon Nanosheets Prepared from Plastic Wastes for Supercapacitors

Wang

Liu

Zhang

et al. 2018

Journal of Elec Materi

View full text Add to dashboard Cite

“…[22] For example, single-and bi-layered porous graphene nanosheets can be obtained using porous and polygonal-shaped MgO layers as templates. [23] The as-obtained graphene nanosheets showed a porous nanomesh structure with a pore-size distribution ranging from 6 to 10 nm, and a high SSA of 1654 m 2 g −1 . Zhu et al proposed a universal salt-templating method to fabricate the graphitic CNS with vertical orientation and further integration of metal carbide on the CNS (MC@CNS).…”

Section: Template-directed Synthesismentioning

confidence: 99%

Holey 2D Nanomaterials for Electrochemical Energy Storage

Peng

Fang

Zhu

et al. 2017

Advanced Energy Materials

326

198

View full text Add to dashboard Cite

2D nanomaterials provide numerous fascinating properties, such as abundant active surfaces and open ion diffusion channels, which enable fast transport and storage of lithium ions and beyond. However, decreased active surfaces, prolonged ion transport pathway, and sluggish ion transport kinetics caused by self‐restacking of 2D nanomaterials during electrode assembly remain a major challenge to build high‐performance energy storage devices with simultaneously maximized energy and power density as well as long cycle life. To address the above challenge, porosity (or hole) engineering in 2D nanomaterials has become a promising strategy to enable porous 2D nanomaterials with synergetic features combining both 2D nanomaterials and porous architectures. Herein, recent important progress on porous/holey 2D nanomaterials for electrochemical energy storage is reviewed, starting with the introduction of synthetic strategies of porous/holey 2D nanomaterials, followed by critical discussion of design rule and their advantageous features. Thereafter, representative work on porous/holey 2D nanomaterials for electrochemical capacitors, lithium‐ion and sodium‐ion batteries, and other emerging battery technologies (lithium‐sulfur and metal‐air batteries) are presented. The article concludes with perspectives on the future directions for porous/holey 2D nanomaterial in energy storage and conversion applications.

show abstract

“…Once GO was doped using strategies either solution-or vapor-based [9,27,32], the reduction of GO mostly happened, causing defunctionalization of GO and degradation of the operability of graphene sheet [37][38][39], which may possibly result in failing of crumpling state. While, it is believed that dopant types could be simply tuned following bottom-up solution-based strategy without crumpled structure compromise, especially for the strategy applying solid templates [40][41][42].…”

Section: Introductionmentioning

confidence: 99%

N-doped crumpled graphene: bottom-up synthesis and its superior oxygen reduction performance

Zhang

Jin

et al. 2016

Sci. China Mater.

View full text Add to dashboard Cite

The crumpled graphene (CrG) was fabricated by applying defluorination of polyvinylidenefluoride (PVDF) on highly curved surface of CaC2 particle through bottom-up synthetic strategy. The limited reaction depth between PVDF and CaC2 leads to the formation of CrG with thin layer (3−6 layer graphene) and reasonable high specific surface area (~324.8 m 2 g −1 ). CrG with N incorporation (N-CrG) was applied as electrode material for reducing oxygen (i.e., oxygen reduction reaction, ORR) in alkaline, showing close onset potential to that of Pt/C and better mass-diffusion behavior. Surprisingly, with increased mass loading of catalysts, N-CrG exhibits steady current increase while Pt/C shows clear current plateau. Meanwhile, the N-CrG sample reveals high cycling stability and tolerance to contaminant, demonstrating its high potential for practical applications. Additionally, the bottom-up synthetic pathway to CrG via polymer dehalogenation on solid alkaline may find more applications which require controlled morphology and thickness of deposited thin graphitic carbon layers.

show abstract

Template‐Directed Synthesis of Pillared‐Porous Carbon Nanosheet Architectures: High‐Performance Electrode Materials for Supercapacitors

Cited by 277 publications

References 32 publications

Porous Carbon Nanosheets Prepared from Plastic Wastes for Supercapacitors

Porous Carbon Nanosheets Prepared from Plastic Wastes for Supercapacitors

Holey 2D Nanomaterials for Electrochemical Energy Storage

N-doped crumpled graphene: bottom-up synthesis and its superior oxygen reduction performance

Contact Info

Product

Resources

About