Template Synthesis into Gelatin-Immobilized Matrix as Perspective Method of Obtaining Supramolecular Macroheterocyclic Compounds

Михайлов, О. В.; Kazymova, Marina A.; Чачков, Д. В.

doi:10.6060/mhc2008.1.90

Cited by 13 publications

(4 citation statements)

References 14 publications

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“…Rather recently in ( 64 – 69 ), the ‘soft’ self-assembly in the Cu(II)–dithiomalonamide–formaldehyde, Cu(II)–dithiomalonamide–acetone, and Cu(II)–thiocarbohydrazide–acetone systems was observed. According to the data of works cited above, in the first of these systems the process according to the scheme ( 3 .9) with the formation of the Cu(II) ( 666 ) complex with 3,9-dithio-4,8-diaza-6-oxaundecadithioamide-1,11 L4 occurs;…”

Section: Self-assembly Of Aza- and Azathiamacrocyclic Metal Chelatmentioning

confidence: 92%

“…Most likely, this is the reason that when copper(II) hexacyanoferrate (II) is replaced by the nickel(II) compound of a similar structure, no process of self-assembly ( 3 .9– 3 .11) is implemented. When Co(II) plays the role of the template, the character of the proceeding processes is apparently somewhat different, but no detailed information on this subject is available in the literature ( 69 ).…”

Section: Self-assembly Of Aza- and Azathiamacrocyclic Metal Chelatmentioning

confidence: 99%

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Molecular nanotechnologies of gelatin-immobilization using macrocyclic metal chelates

Михайлов

2014

Nano Reviews

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This article is a review of recent developments in the self-assembled nanostructures based on chelate coordination compounds. Molecular nanotechnologies of self-assembly of 3d-element aza- and thiazametalmacrocyclic complexes that happen in nanoreactors on the basis of metal hexacyanoferrate(II) gelatin-immobilized matrix under their contact with water solutions containing various (N,O,S)-donor atomic ligands and organic compounds having one or two carbonyl groups have been considered in this review. It has been noted that the assortment of macrocyclic metal chelates obtained as a result of using molecular nanotechnologies in such specific conditions considerably differs from the assortment of metal chelates formed at the conditions traditional for chemical synthesis.

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Section: Self-assembly Of Aza- and Azathiamacrocyclic Metal Chelatmentioning

confidence: 92%

Section: Self-assembly Of Aza- and Azathiamacrocyclic Metal Chelatmentioning

confidence: 99%

Molecular nanotechnologies of gelatin-immobilization using macrocyclic metal chelates

Михайлов

2014

Nano Reviews

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“…Достаточно доступные октаалкилпорфирины 4 не могут быть Такие порфирины получаются в основном путем конденсации α-незамещенных линейных производных пирролов с бензальдегидами. [12,13] Следует заметить, что функционализированные 5,15-диарилокталкилпорфирины 5, при закреплении на полимере-носителе выполняют роль сшивающего агента и в конечном итоге приводят к получению структурированных материалов, в которых тетрапиррольные макрогетероциклы в значительной степени экранированы макромолекулярным окружением и степень подвижности их снижена. В связи с этим в качестве иммобилизантов наибольший интерес представляют монозамещенные порфирины.…”

Section: порфирины Porphyrinsunclassified

“…Общие подходы к синтезу мезо-фенилпорфиринов обобщены в обзоре. [12] Направленная функционализация порфиринов определяется выбором полимера-носителя, что в итоге является определяющим фактором для успешного закрепления порфирина или его металлокомплекса. Исходный полимер-носитель выбирается или конструируется с заранее заданными свойствами (определенной растворимостью, заданной молекулярной массой и молекулярно-массовым распределением).…”

Section: порфирины Porphyrinsunclassified

Synthesis of Molecular Synthons for Porphyrinpolymers

Агеева¹,

Сырбу²,

Койфман³

2009

MHC

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Peculiarities of the unique structure of porphyrins, possibilities of their peripheral functionalization, ability of metal complexes to extracoordination allow to use them for inclusion in porphyrin-polymer systems in order to endow them with specific properties, determined by tetrapyrrole macrocyclic compounds and their complexes. Porphyrins and their analogues being immobilised on a polymer carrier not only preserve their useful properties, but even strengthen them due to cooperative interactions in polymer chains, separation of active centres, increase of stability of tetrapyrrole fragments This review systematise methods of synthesis of meso-phenyl substituted porphyrins which can be used for fastening on a polymer-carrier. The general approaches to functionalization of porphyrin monomers and their immobilization on synthetic polymers by macromolecular reactions and copolymerization are considered. Strategy of porphyrin-polymer syntheses is based on the previoiusly obtained regularities of mutual influence of the structure of tetrapyrrolic macroheterocycles and polymer-carriers and their ability to self-organization.

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Porphyrins with Phenolic Fragments at the Periphery of the Macrocycle as Perspective Antioxidants, Cytoprotectors and Heavy Metal Scavengers

Kolyada

Осипова

Берберова

et al. 2021

Chem Heterocycl Comp

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Template Synthesis into Gelatin-Immobilized Matrix as Perspective Method of Obtaining Supramolecular Macroheterocyclic Compounds

Cited by 13 publications

References 14 publications

Molecular nanotechnologies of gelatin-immobilization using macrocyclic metal chelates

Molecular nanotechnologies of gelatin-immobilization using macrocyclic metal chelates

Synthesis of Molecular Synthons for Porphyrinpolymers

Porphyrins with Phenolic Fragments at the Periphery of the Macrocycle as Perspective Antioxidants, Cytoprotectors and Heavy Metal Scavengers

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