We present an approach to single-shot high-fidelity preparation of an nqubit state based on neighboring optimal control theory. This represents a new application of the neighboring optimal control formalism which was originally developed to produce single-shot high-fidelity quantum gates. To illustrate the approach, and to provide a proof-of-principle, we use it to prepare the two qubit Bell statewith an error probability ε ∼ 10 −6 (10 −5 ) for ideal (non-ideal) control. Using standard methods in the literature, these high-fidelity Bell states can be leveraged to fault-tolerantly prepare the logical state |β 01 .