Ternary (liquid+liquid) equilibria for (acetonitrile+ethanol or 1-propanol+heptane) and (aniline+methanol+cyclohexane)

Phase equilibria of water+1-propanol+solvent (n-amyl acetate, cyclohexanol, and cyclohexyl acetate) at T=298.2K

“…The (liquid-liquid) equilibrium (LLE) measurements and phase behavior of ternary systems including alcohols were presented in the literature [1][2][3][4][5][6][7]. Since the mixture of 1-propanol and water forms a minimum azeotrope at T = 360.80 K and x aze 1-propanol = 0.432 (mole fraction) [8], solvent extraction is preferred to separate 1-propanol from aqueous solutions.…”

Liquid-Liquid Phase Behavior of Acetonitrile and Normal Alkanes

“…The full dataset, including also mass fractions, is listed in Table . Figure a–c shows the LLE of ACN with n -hexane, n -heptane, and n -octane measured in this work, together with data available in the literature. ,− , Figure d shows the LLE of those systems together with the data of the ACN– n -decane system, for which only the sector in the vicinity of the critical point was determined, as the determination of the full LLE of this system was not the objective of this work. The detailing of the redetermined systems allows for an adequate grading of the ACN– n -octane mixture within the other members of the ACN– n -alkane “family”.…”

“…When experimental data are only available in the critical region (∼±2–5 K), these differences cannot be seen. Data from the literature ,− for the mixtures studied here were included in the plots of the LLE (cf., Figure ). They do agree quite well with the present work, although some discrepancies are noticeable when checking the data in more detail.…”

“…Isobaric LLE data obtained in this study (colored and black symbols) together with data from the literature (white and gray symbols). ,− ,,,, For further details, consider Table . The curves shown are fitting results from eq .…”

Phase Equilibria of Ternary and Quaternary Systems Containing Diethyl Carbonate with Water

“…The measured LLE results were correlated by using the modified and extended UNIQUAC models [7, 8] having binary, ternary, and quaternary parameters. The binary energy parameters for completely miscible binary mixtures were obtained from experimental vapor–liquid equilibria (VLE) data [9–14]. The binary energy parameters for partially miscible binary mixtures were obtained from mutual solubility data [15–17].…”