Ternary (liquid + liquid) equilibrium experiment and thermodynamic modeling for extraction of diethoxymethane from water with different solvents at 303.2 K under 101.3 kPa

Li, Qingsong; Guo, Hongyue; Lin, Song; Zhao, Yicong; Li, Hui

doi:10.1016/j.molliq.2021.116793

Cited by 8 publications

(2 citation statements)

References 36 publications

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“…The standard uncertainties for the components of the specimens were calculated by using GUM and the relevant standards. The formulas are as follows: x̅ = 1 n ∑ n i = 1 x i S 2 false( q i false) = ∑ i = 1 n false( q i − true q − ) 2 n − 1 u = S false( q i false) n where χ i is the i th experimental value, n is the number of samples, S ( q k ) is standard for experimental deviation, and u represents standard uncertainty.…”

Section: Methodsmentioning

confidence: 99%

Extraction of Isobutanol from Aqueous Solution by Four Solvents: Liquid–Liquid Phase Equilibrium Measurements and Thermodynamic Modeling Studies

Li,

Shao,

Gao

et al. 2024

J. Chem. Eng. Data

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To solve the problem of treating isobutanol-containing wastewater in industrial production, four relatively green solvents (hexamethyldisiloxane, isopentyl acetate, ethyl acetate, and propylene carbonate) were selected as the extractants for the separation of water and isobutanol. Liquid−liquid equilibrium (LLE) data for water + isobutanol + hexamethyldisiloxane/isopentyl acetate/ethyl acetate/propylene carbonate were measured at 298.2 K and 101.3 kPa. The extraction performance of the four extractants was evaluated by the distribution coefficient (D) and separation factor (S). Meanwhile, the experimental LLE data were fitted using NRTL and UNIQUAC models to obtain the regression parameters. Mixed-surface analysis based on Gibbs energy topology verified the reliability of the binary interaction parameters. The root-meansquare deviation (RMSD) of the NRTL and UNIQUAC models was less than 0.0045 and 0.0059, respectively, which indicated that the NRTL and UNIQUAC models were suitable for the study of this system.

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Section: Methodsmentioning

confidence: 99%

Extraction of Isobutanol from Aqueous Solution by Four Solvents: Liquid–Liquid Phase Equilibrium Measurements and Thermodynamic Modeling Studies

Li,

Shao,

Gao

et al. 2024

J. Chem. Eng. Data

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“…As can be seen in Table 4, every R 2 value is greater than 0.99, demonstrating the high dependability of the experimental data. 38…”

Section: Lle Data Tablesmentioning

confidence: 99%

Liquid–Liquid Equilibrium Measurement and Thermodynamic Modeling for the Ternary System of Water + Epichlorohydrin + Solvents (n-Propyl Acetate, 2-Ethyl-1-hexanol) at Different Temperatures

et al. 2023

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To separate and purify epichlorohydrin from water, the liquid–liquid equilibrium (LLE) data of water + epichlorohydrin + solvents (n-propyl acetate, 2-ethyl-1-hexanol) at 303.2, 313.2, and 323.2 K were measured at 101.3 kPa. The extraction ability of an extractant was evaluated using the distribution coefficient (D) and selectivity factor (S). Simultaneously, the Bachmann and Hand equations were used to verify the accuracy of the liquid–liquid equilibrium data. The NRTL and UNIQUAC models successfully correlated the LLE data, and the root mean square deviation for each model was less than 0.50%. Finally, GUI-MATLAB tools were employed to confirm that the regression parameters of the thermodynamic model areconsistent.

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Liquid–Liquid Equilibria Data and Thermodynamic Modeling of {Mesityl Oxide + Diethoxymethane + Water} Ternary System at 303.15, 313.15, 323.15 K Under 101.325 kPa

Guo,

Li,

et al. 2024

J Solution Chem

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Ternary (liquid + liquid) equilibrium experiment and thermodynamic modeling for extraction of diethoxymethane from water with different solvents at 303.2 K under 101.3 kPa

Cited by 8 publications

References 36 publications

Extraction of Isobutanol from Aqueous Solution by Four Solvents: Liquid–Liquid Phase Equilibrium Measurements and Thermodynamic Modeling Studies

Extraction of Isobutanol from Aqueous Solution by Four Solvents: Liquid–Liquid Phase Equilibrium Measurements and Thermodynamic Modeling Studies

Liquid–Liquid Equilibrium Measurement and Thermodynamic Modeling for the Ternary System of Water + Epichlorohydrin + Solvents (n-Propyl Acetate, 2-Ethyl-1-hexanol) at Different Temperatures

Liquid–Liquid Equilibria Data and Thermodynamic Modeling of {Mesityl Oxide + Diethoxymethane + Water} Ternary System at 303.15, 313.15, 323.15 K Under 101.325 kPa

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