“… [32] Regarding organo‐functionalized clusters, a synthesis from mononuclear compounds is possible, [33] but most of the reported clusters were synthesized by transformations of binary cage compounds of the general formulas [(RSn) 4 E 6 ] or [(RSn) 3 E 4 Cl] (R=organic substituent, E=S, Se). [ 34 , 35 , 36 , 37 , 38 , 39 , 40 ] One of the first compounds of this type, [(CuPPhMe 2 ) 6 (PhSnS 3 ) 2 ], [40] was synthesized by using [Cu(PPhMe 2 )bipyCl] (bipy=2,2’‐bipyridine) as the source of Cu atoms, while fragmentation of the heteroadamantane compound [(PhSn) 4 S 6 ] with Na 2 S formed [PhSnS 3 ] 3− in situ, as the source of the RSn units. [41] This was the first example of the inorganic cluster core archetype [(CuPPh 3‐x R′ x ) 6 (RTE 3 ) 2 ] (x=0, 1, 2), consisting of six Cu atoms arranged in a chair conformation that is connected to two TE 3 groups to obtain an overall spherical architecture.…”