Ternary nanohybrid of reduced graphene oxide-nafion@silver nanoparticles for boosting the sensor performance in non-enzymatic amperometric detection of hydrogen peroxide

Yusoff, Norazriena; Rameshkumar, Perumal; Mehmood, Muhammad Shahid; Pandikumar, Alagarsamy; Lee, Hing Wah; Huang, Nay Ming

doi:10.1016/j.bios.2016.09.045

Cited by 110 publications

(46 citation statements)

References 36 publications

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“…The LOD of H2O2 is given in Table 1. It can be seen from Table 1 that the LODs obtained from different techniques are quite comparable with each other, and are much lower than the already reported data [34][35][36][37]. It can be concluded from these results that electrodeposited PACHA and PANI on the surface of an Au electrode enables the detection of H2O2 at a low concentration level.…”

Section: Electrochemical Response With Increase In Concentrationsupporting

confidence: 74%

Enhanced Electrocatalytic Behaviour of Poy(aniline-co-2-hydroxyaniline) Coated Electrodes for Hydrogen Peroxide Electrooxidation

2019

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Polymer-coated electrodes are widely used for the detection and oxidation of hydrogen peroxide (H 2 O 2 ). Conducting polyaniline (PANI), poly (2-hydroxyanilne) (PHA), and their copolymer poly(aniline-co-2-hydroxyaniline) (PACHA) were electrochemically synthesized on a gold substrate for H 2 O 2 detection and analysis. Cyclic voltammetry (CV), square wave voltammetry (SWV), and differential pulse voltammetry (DPV) techniques were used for electroanalysis. Both PACHA and PANI greatly reduced the gold overpotential for H 2 O 2 oxidation with enhanced current densities. The PACHA-and PANI-coated electrodes showed oxidative peaks at 0.30 and 0.50 V, respectively, in the presence of 1.4 × 10 −6 M H 2 O 2 , while PHA-coated electrodes exhibited no response. The fabricated electrodes displayed a linear response towards H 2 O 2 in range of 2 × 10 −7 to 1.4 × 10 −6 M, with very low detection limits (LODs) of 1 × 10 −7 M (for PACHA) and 1.15 × 10 −7 M (for PANI) evaluated from CV data. In case of SWV and DPV, the LODs were found to be 1.78 × 10 −7 M (for PACHA) and 1 × 10 −7 M (for PANI), respectively. The materials exhibit high sensitivity of 650 A/Mcm 2 and show good stability. The PACHA-coated electrode shows better capacitance (1.84 × 10 −3 F) than PHA-(2.52 × 10 −4 F) and PANI-coated (1.17 × 10 −3 F) electrodes.

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Section: Electrochemical Response With Increase In Concentrationsupporting

confidence: 74%

Enhanced Electrocatalytic Behaviour of Poy(aniline-co-2-hydroxyaniline) Coated Electrodes for Hydrogen Peroxide Electrooxidation

2019

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“…Amperometric sensors are miniaturized devices, which can detect target analytes sensitively, rapidly, and economically. The development of different types of amperometric sensors has attracted great attentions for a wide range of applications in medical diagnosis, food safety, defense, and environmental monitoring , , . Amperometric sensors can be constructed based on various electrodes, such as Clark oxygen electrodes , , and screen‐printed thick film electrodes , , .…”

Section: Introductionmentioning

confidence: 96%

Flexible Glass‐based Amperometric Sensors for Hydrogen Peroxide

2017

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The development of flexible sensors could enable significant advances in clinical diagnosis, defense, and environmental monitoring. Flexible glass provides the flexibility and possesses stable chemical and physical properties. Here, we show that carbon graphite and silver/silver chloride inks can be printed onto flexible glass to construct amperometric sensors, and the sensors show sensitive and rapid detections of hydrogen peroxide. We anticipate that these results could provide exciting avenues for fundamental studies of flexible electronics and flexible bioelectronics, as well as a variety of applications in fields ranging from medical diagnosis to defense.

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“…GRO has been widely used in biosensor applications due to its easy dispersion ability, high surface area, biocompability, electrocatalytic properties, mechanical strength and facile surface modification capability for bioconjugation . Therefore, a variety of GRO‐based materials, such as GRO‐metal nanoparticle composite , GRO‐carbon nanotube composite , GRO‐metal oxide nanoparticle composite and GRO‐polymer composite have been investigated to produce a synergetic effect and proven to be effective as electrochemical biosensors.…”

Section: Introductionmentioning

confidence: 99%

Amperometric Biosensors for Tyramine Determination Based on Graphene Oxide and Polyvinylferrocene Modified Screen‐printed Electrodes

et al. 2019

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A comparison of the analytical characteristics of two tyramine biosensors, based on graphene oxide (GRO) and polyvinylferrocene (PVF) modified screen‐printed carbon electrodes (SPCE), is reported. Diamine oxidase (DAOx) or monoamine oxidase (MAOx) was immobilized onto the PVF/GRO modified SPCE to fabricate the biosensors. Surface characteristics and electrochemical behaviour of the modified SPCEs were investigated by atomic force microscopy (AFM), scanning electron microscopy (SEM), energy dispersive X‐ray spectroscopy (EDX) and cyclic voltammetry (CV). Electrode surface composition and experimental variables such as pH and working potential were optimized in order to ensure a high performance. Under optimum experimental conditions, both DAOx/PVF/GRO/SPCE and MAOx/PVF/GRO/SPCE biosensors exhibited wide linear dynamic ranges for tyramine from 9.9×10−7 to 1.2×10−4 M and from 9.9×10−7 to 1.1×10−4 M, respectively. MAOx/PVF/GRO/SPCE biosensor showed higher sensitivity (11.98 μA mM−1) for tyramine determination than the DAOx/PVF/GRO/SPCE biosensor (7.99 μA mM−1). The substrate specifity of the biosensors to other biogenic amines namely histamine, putrescine, spermine, spermidine, tryptamine, β‐phenylethylamine and cadaverine was also investigated. The developed biosensors were successfully used for tyramine determination in cheese sample.

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Ternary nanohybrid of reduced graphene oxide-nafion@silver nanoparticles for boosting the sensor performance in non-enzymatic amperometric detection of hydrogen peroxide

Cited by 110 publications

References 36 publications

Enhanced Electrocatalytic Behaviour of Poy(aniline-co-2-hydroxyaniline) Coated Electrodes for Hydrogen Peroxide Electrooxidation

Enhanced Electrocatalytic Behaviour of Poy(aniline-co-2-hydroxyaniline) Coated Electrodes for Hydrogen Peroxide Electrooxidation

Flexible Glass‐based Amperometric Sensors for Hydrogen Peroxide

Amperometric Biosensors for Tyramine Determination Based on Graphene Oxide and Polyvinylferrocene Modified Screen‐printed Electrodes

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