2023
DOI: 10.1515/zkri-2023-0014
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Ternary orthorhombic Laves phases Sr2Pd3Sn, Eu2Pd3Sn and Eu2Pd3In

Abstract: The ternary Laves phases Sr2Pd3Sn, Eu2Pd3Sn and Eu2Pd3In were synthesized by induction melting of the elements in sealed tantalum ampoules. The polycrystalline products were characterized through their powder X-ray diffraction patterns. The structure of Eu2Pd3Sn was refined from single crystal X-ray diffractometer data: Mg2MnGa3 type, Cmcm, a = 583.36(5), b = 908.31(7), c = 958.06(8) pm, wR2 = 0.0366, 557 F 2 values, 23 variables. The palladium and tin atoms show the inverse coloring on the n… Show more

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“…It is interesting to note, that the inverse coloring has been observed for the stannide Eu 2 Pd 3 Sn and the isotypic compounds Sr 2 Pd 3 Sn and Eu 2 Pd 3 In. [126] The coloring variants of both compounds are [93][94][95][96] The indices for the klassengleiche (k) and translationengleiche (t) symmetry reductions and the unit cell transformations are given. shown in Figure 18.…”
Section: Mgzn 2 Superstructuresmentioning
confidence: 99%
“…It is interesting to note, that the inverse coloring has been observed for the stannide Eu 2 Pd 3 Sn and the isotypic compounds Sr 2 Pd 3 Sn and Eu 2 Pd 3 In. [126] The coloring variants of both compounds are [93][94][95][96] The indices for the klassengleiche (k) and translationengleiche (t) symmetry reductions and the unit cell transformations are given. shown in Figure 18.…”
Section: Mgzn 2 Superstructuresmentioning
confidence: 99%