The
occurrence forms of trace elements in coal are of great significance
for the clean utilization, abnormal enrichment, and recovery of beneficial
elements in coal. The Fushun Basin in Northeast China has thick coal
deposits which provide a good opportunity for studying their geochemistry.
This study aims to estimate the element enrichment of Paleogene coal
seams and their influencing factors during deposition based on statistical
and geochemical analyses. Compared with world hard coals, coals in
the Fushun Basin feature enrichment of Ga and Sb (CC > 5), slight
enrichment of V, Cr, Co, Ni, As, Rb, Zr, Nb, and Cd (2 < CC <
5), and depletion of B, Tl, Bl, and U (CC < 0.5). The CC values
of the remaining elements (0.5 < CC < 2) are close to the average
values for world hard coals. The main carriers of Ga, Co, Rb, Mo,
As, Se, Pb, V, and Li are potassium, iron, and sulfate minerals and
those of Cd, Cr, Ni, Sb, Th, Sn, U, Hf, Zr, Cs, Ta, and Nb are clay
minerals. The CIA, Sr/Cu, Rb/Sr, and Ga/Rb values suggest that the
studied coal seam formed under humid/warm climatic conditions. The
coal seam is mainly derived from intermediate source rocks and sandstone
or mudstone source rocks which were exposed to intensive chemical
weathering and deposited in a freshwater setting. Additionally, paleoweathering,
paleoclimate, detrital input, and provenance all contributed to the
enrichment of geochemical elements in the studied Paleogene coal.
The results of this study are preliminary, and the authors will continue
to conduct mineralogical analysis.