known that the optical properties related refractive index is an important parameter for ordered micro/nanostructures. Commonly, organic substances own lower refraction. Aiming at improving which, researchers introduce highly polarizable heteroatoms or rigid aromatic moieties. However, the maximum of refractive index is limited to 1.54-1.60, [3] which is far from the requirements of rapidly developing technologies. [4] Incorporation of inorganic materials with relative higher refractive index (TiO 2 , ZnO, ZnS, graphene nanoparticles, and Si) into an organic matrix is capable of enlarging the optical parameters to a great extent, generally up to a value of 2.5-3.0, [5] which offers more chances for the fabrication of novel ordered micro/nanostructures. Photonic crystals (PCs), for example, regularly arrange materials of high and low dielectric constants on the order of the wavelength of light. The photonic bandgap (PBG) prohibiting the propagation of light results from the sufficient dielectric contrast and appropriate geometry. The structural color therefore generates. Manipulating the propagation of light via micro/nanostructures meets the requirements for modern optical devices. [6] As a result, more efforts have been applied to devices consisting of micro/nanostructures of multiple materials, such as synthetic materials and biomaterials. [7] Besides optical properties, the strength and toughness of ordered micro/nanostructures are also improved based on the hybrid material. Meanwhile, the electric and magnetic features of inorganic dopants can also exactly assist the adjustability. Therefore, the hybrid can significantly improve performance compared with its constituent.This review emphasizes on applications sought (sensing, imaging, communication, photoelectricity, etc.), the materials used (silicon, metals, polymers, etc.), and the preparation methods employed (patterning, etching, deposition, etc.). We present an attempt to classify and compare some intensively reported micro/nanostructures of hybrid materials and/or heterogeneous structures, along with recent important developments in literatures. It is organized as follows: First, we summarize some fundamental physical principles and concepts in brief. Second, we particularly highlight artificial and natural laminar structures, represented by Bragg stacks (BSs) and butterfly wings, which have drawn much attention in the latest literatures. Next, the focus shifts to the preparation routes and materials adoption of colloidal crystals and their derived periodic arrays. A few examples of highly functional materials Recent advances in manufacturing and technology of ordered hybrid micro/ nanostructures have acquired many breakthroughs. With the aid of the cooperation of various materials, the ordered hybrid micro/nanostructures exhibit high-quality performance and mechanical stability and allow the modulation on the light-matter interaction in a controllable manner, thereby enabling a wide variety of innovative applications. This article reviews recent deve...