We study CPT-odd non-minimal Lorentz-symmetry violating couplings in the electroweak sector modifying the interactions between leptons, gauge mediators and the Higgs boson. The tree-level (differential) cross sections for three important electroweak processes are discussed: e + e − → Z H, e + e − → Z Z and γ γ → W + W − . By considering next-generation e + e − colliders reaching centerof-mass energies at the TeV scale and the estimated improved precision for the measurements of the respective cross sections, we are able to project upper bounds on the purely time-like background 4-vector as strict as 10 −5 GeV −1 , in agreement with previous work on similar Lorentz-violating couplings.