Tetraacuo-bis-(N,N-dimethylacetamide-O)magnesium(II) chloride dihydrate. An option to improve magnesium effect on phosphatase stimulation and albumin binding

Martini, Nancy; Parente, Juliana Elena; Restrepo-Guerrero, Gonzalo; Franca, Carlos A.; Piro, Oscar E.; Echeverría, Gustavo A.; Williams, Patricia Ana María; Ferrer, Evelina G.

doi:10.1016/j.molstruc.2020.129240

Cited by 2 publications

(1 citation statement)

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“…[13] As a macroelement component of many enzymes, Mg has little toxicity to human body. [14] The atomic radius of Mg was moderate, made it easy to coordinate with organic molecules to prepare organomagnesium compounds. [15] The design, synthesis, and study of Mg fluorescent complexes enriched the metal coordination chemistry and contributed to the acquisition of useful fluorescent materials with luminescent properties.…”

Section: Introductionmentioning

confidence: 99%

Organometallic Magnesium Complex with Aggregation Induced Emission Properties: Synthesis, Characterization, and Fluorescent Fibers Applications

Fang

et al. 2022

ChemPhysChem

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In this work, a novel organomagnesium complex with outstanding aggregation induced emission (AIE) properties is synthesized using dibenzoylmethane (DBM) as the ligand. The structure of the complex is confirmed to be one magnesium ion coordinated to the dione groups of two DBM molecules, and the magnesium ion adopts a distorted octahedrally geometry. The obvious emission is found for Mg(DBM) 2 powder and not in the solution, making this the first reported organomagnesium complex with AIE property. The properties of the complex were investigated by using UV-vis absorption and fluorescence emission spectroscopy, cyclic voltammetry, and density func-tional theory calculations. Moreover, the Mg(DBM) 2 solution dispersed in filter paper was is colorless, which may be made into a convenient anti-counterfeiting and encryption tool. Mg(DBM) 2 /alginate fibers were prepared by wet-spinning process and further processed into paper, which can be used in the fields of sensors, anti-counterfeiting, and encryption. Sweat contains a wealth of chemical information that could potentially indicate the body's deeper biomolecular state. The prepared fluorescent fibers were used to detect sweat due to its nontoxic, low-cost efficient and fast response to analytes.

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Section: Introductionmentioning

confidence: 99%