Tetrabutylammonium 2,6-dihydroxybenzoate 2,6-dihydroxybenzoic acid solvate

The title molecular salts, N(2)H(5)(+)·C(7)H(5)O(3)(-)·C(7)H(6)O(3) and N(2)H(5)(+)·C(11)H(7)O(3)(-)·C(11)H(8)O(3), are acid adducts containing a hydrazinium cation, one molecule of a deprotonated acid and one molecule of a neutral acid. The two compounds contain essentially identical hydrogen-bond networks between the hydrazinium cation and the acid molecules, which define closely comparable two-dimensional layers in the structures. The planes of the aromatic rings within both structures are approximately parallel and the layers are stacked with comparable intermolecular interactions.

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Tetrabutylammonium 2,6-dihydroxybenzoate 2,6-dihydroxybenzoic acid solvate

Abstract: Key indicatorsSingle-crystal X-ray study T = 180 K Mean '(C±C) = 0.005 A Ê R factor = 0.043 wR factor = 0.113 Data-to-parameter ratio = 11.8For details of how these key indicators were automatically derived from the article, see

Cited by 4 publications

References 14 publications

‘Wet chemistry’ and crystallochemistry reasons for acidic matrix suppression by quaternary ammonium salts under matrix‐assisted laser desorption/ionization conditions

‘Wet chemistry’ and crystallochemistry reasons for acidic matrix suppression by quaternary ammonium salts under matrix‐assisted laser desorption/ionization conditions

Pseudosymmetric layers in high-Z′ and P1 structures of organic molecules

The acid adducts hydrazinium 2-hydroxybenzoate–2-hydroxybenzoic acid (1/1) and hydrazinium 3-hydroxy-2-naphthoate–3-hydroxy-2-naphthoic acid (1/1)

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