Tetrabutylammonium hydrogen phenylarsonate–phenylarsonic acid (1/1)

Reck, Lukas; Schmitt, Wolfgang

doi:10.1107/s1600536812035362

Acta Cryst E

2012

DOI: 10.1107/s1600536812035362

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Tetrabutylammonium hydrogen phenylarsonate–phenylarsonic acid (1/1)

Lukas Reck

Wolfgang Schmitt

Abstract: The structure of the title salt adduct, (C4H9)4N+·C6H5AsO3H−·C6H5AsO3H2, features chains along the a axis comprising alternating hydrogen phenylarsonate anions and phenylarsonic acid molecules linked by O—H⋯O hydrogen bonds.

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2023

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Crystal structure of dibenzylammonium hydrogen (4-aminophenyl)arsonate monohydrate

Traoré,

Diallo,

Sidibé

et al. 2023

Acta Cryst E

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The title salt, C14H16N+·C6H7AsNO3 −·H2O or [(C6H5CH2)2NH2][H2NC6H4As(OH)O2]·H2O, (I), was synthesized by mixing an aqueous solution of (4-aminophenyl)arsonic acid with an ethanolic solution of dibenzylamine at room temperature. Compound I crystallizes in the monoclinic P21/c space group. The three components forming I are linked via N—H...O and O—H...O intermolecular hydrogen bonds, resulting in the propagation of an infinite zigzag chain. Additional weak interactions between neighbouring chains, such as π–π and N—H...O contacts, involving phenyl rings, –NH2 and –As(OH)O3 functions, and H2O, respectively, lead to a three-dimensional network.

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Crystal structure of dibenzylammonium hydrogen (4-aminophenyl)arsonate monohydrate

Traoré,

Diallo,

Sidibé

et al. 2023

Acta Cryst E

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show abstract

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Tetrabutylammonium hydrogen phenylarsonate–phenylarsonic acid (1/1)

Abstract: The structure of the title salt adduct, (C4H9)4N+·C6H5AsO3H−·C6H5AsO3H2, features chains along the a axis comprising alternating hydrogen phenylarsonate anions and phenylarsonic acid molecules linked by O—H⋯O hydrogen bonds.

Cited by 1 publication

References 11 publications

Crystal structure of dibenzylammonium hydrogen (4-aminophenyl)arsonate monohydrate

Crystal structure of dibenzylammonium hydrogen (4-aminophenyl)arsonate monohydrate

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Tetrabutylammonium hydrogen phenylarsonate–phenylarsonic acid (1/1)

Abstract: The structure of the title salt adduct, (C4H9)4N+·C6H5AsO3H−·C6H5AsO3H2, features chains along the a axis comprising alternating hydrogen phenyl­arsonate anions and phenyl­arsonic acid mol­ecules linked by O—H⋯O hydrogen bonds.

Cited by 1 publication

References 11 publications

Crystal structure of dibenzylammonium hydrogen (4-aminophenyl)arsonate monohydrate

Crystal structure of dibenzylammonium hydrogen (4-aminophenyl)arsonate monohydrate

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Product

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Abstract: The structure of the title salt adduct, (C4H9)4N+·C6H5AsO3H−·C6H5AsO3H2, features chains along the a axis comprising alternating hydrogen phenylarsonate anions and phenylarsonic acid molecules linked by O—H⋯O hydrogen bonds.