2009
DOI: 10.1107/s1600536809046327
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Tetracarbonylbis(η5-cyclopentadienyl)bis[(dec-9-en-1-yl)diphenylphosphine]dimolybdenum(0)(MoMo) tetrahydrofuran disolvate

Abstract: The asymmetric unit of the title compound, [Mo2(η5-C5H5)2(C22H29P)2(CO)4]·2C4H8O, contains two half-mol­ecules of the organometallic species and two solvent mol­ecules. Both organometallic mol­ecules are completed by crystallographic inversion symmetry, yielding dimeric units with Mo—Mo single-bond lengths of 3.2703 (6) and 3.2548 (6) Å. Each Mo atom is also coordinated by an η5-cyclo­pentdienyl ligand, two carbonyl ligands, and a (dec-9-en-1-yl)diphenyl­phosphine ligand.

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