Tetrakis[3,5-bis(trifluoromethyl)phenyl]borate. Highly Lipophilic Stable Anionic Agent for Solvent-extraction of Cations

Nishida, Hiroshi; Takada, Naoko; Yoshimura, Masaji; Sonoda, Takaaki; Kobayashi, Hiroshi

doi:10.1246/bcsj.57.2600

Cited by 381 publications

(201 citation statements)

References 17 publications

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“…Nitrite, NO;, was determined with 1.8 mg aquocyanocobalt(III)-hepta(2-phenylethyl)cobyrinate perchlorate (Fluka 72590), 117.9 mg o-NPOE, 0.2 mg potassium tetrakis[3,5-bis(trifluoromethyl)phenyl]borate (K(TFPB), Fluka 60588; Nishida et al 1984), and 59.4 mg PVC. The electrolyte was 0.01 M NaNO, and 0.01 M NaCl (Stephanek et al 1986;Schaller et al 1994).…”

Section: Notesmentioning

confidence: 99%

High spatial resolution measurements in lake sediments with PVC based liquid membrane ion‐selective electrodes

Müller

Buis

Stierli

et al. 1998

Limnology & Oceanography

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Ion‐selective liquid membrane electrodes for Ca2+, CO32−, NH4+, NO3−, NO2−, and pH have been miniaturized and their characteristics evaluated in view of their application in sediment pore water of lakes. PVC membranes were prepared in polyethylene pipette tips with an end diameter of 0.6 mm. This is a simple method to produce inexpensive disposable ion‐selective electrodes for various applications. Detection limits were 1 µM for Ca2+, CO32−, NH4+, and NO3−, and 10 µM for NO2−. The pH sensor was linear in the pH range of 4–11. Selectivities for Ca2+, CO32− and pH are high enough for the application in seawater. The sensors for NH4+, NO3−, and NO2− in their low concentration range experience interferences from K+, SO42+, and HCO3−, respectively, in lake pore water. Reproducibility in pure solutions is between 20.2 and 20.6 mV, The applicability of the miniaturized sensors are demonstrated in measurements of concentration gradients across the sediment‐water interface in sediment cores of several lakes.

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Section: Notesmentioning

confidence: 99%

High spatial resolution measurements in lake sediments with PVC based liquid membrane ion‐selective electrodes

Müller

Buis

Stierli

et al. 1998

Limnology & Oceanography

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“…Examples include B(OTeF& (2), BlICH17-(1, 3), and B k , -(& = C6H5 (4) or 3,5-C6H3(CF3)? (5)). The interest in such species derives in part from a desire to study coordinatively unsaturated cations such as R3Si+ (6) and Fe(porphyrin)+ (3b), both of which have yet to be prepared and isolated in a condensed phase, and in part from the desire to prepare more active transition metal catalysts (4).…”

Section: Introductionmentioning

confidence: 99%

Preparation and characterization of Tl(1,2-C₂H₄Cl₂)B(OTeF₅)₄: a metal complex of a least coordinating solvent and a least coordinating anion

Hurlburt¹,

Anderson²,

Strauss³

1992

Can. J. Chem.

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. Can. J. Chem. 70, 726 (1992). Addition of B(OTeF,), to TIOTeF, in the weakly coordinating solvents dichloromethane, 1,2-dichloroethane, and 1,1,2-trichlorotrifluoroethane produces solutions of M(solv).,+B(OTeF,),-. When the solvent was 1,2-dichloroethane, the crystalline compound TI( 1 ,2-C2H,Cl2)B(OTeF5), was isolated and studied by X-ray crystallography: triclinic, space group p i , a = 9.221 (4), b = 11.396 (S), c = 12.538 (4) A, cx = 110.75 (3)", P = 101.72 (3)", y = 99.74(3)",Z = 2, T = -116°C. The Tl(1 ,2-C2H,C12)+ cation contains a five-membered chelate ring with T I 4 1 distances of 3.138 (4) and 3.179

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“…30 The NaTFPB salt was synthesized as reported previously. 29,[31][32][33] CTACl (Wako Pure Chemical Ind., No. 038-08402), picric acid (Nacalai Tesque Ind., No.…”

Section: Chemicalsmentioning

confidence: 99%

Propagation and Synchronization of Potential Oscillations in Multiple Liquid Membrane Systems

et al. 2012

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Two liquid membrane oscillators composed of aqueous solutions containing cetyltrimethylammonium chloride (CTACl) and alcohol, W1 and W1′, a nitrobenzene solution containing picric acid, O, and pure water phase, W2, were connected through O and W2 as common phases. Two glass tubes including W1 and W1′ were inserted into the O/W2 interface. Both membrane potential differences between W1 and W2 and that between W1′ and W2 were recorded using a pair of Ag/AgCl electrodes located near the orifice of each tube. The oscillations of two membrane potentials synchronized each other when the distance between the tubes was less than 10 mm. The synchronization was attended by the propagation of a potential pulse from one side to another with an interval of approximately 70 ms at a distance of 10 mm. It was examined whether the propagation of the potential pulse was due to electric conduction in bulk phases, or due to the interfacial conduction by several experiments in the addition of indifferent electrolytes or nonionic surfactant. Consequently, it has been demonstrated that the propagation of oscillation pulse was dominated mainly by the interfacial conduction process, and additionally by the bulk ionic conduction and that the interfacial diffusion and distribution of Cl -played a crucial role.

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Tetrakis[3,5-bis(trifluoromethyl)phenyl]borate. Highly Lipophilic Stable Anionic Agent for Solvent-extraction of Cations

Cited by 381 publications

References 17 publications

High spatial resolution measurements in lake sediments with PVC based liquid membrane ion‐selective electrodes

High spatial resolution measurements in lake sediments with PVC based liquid membrane ion‐selective electrodes

Preparation and characterization of Tl(1,2-C₂H₄Cl₂)B(OTeF₅)₄: a metal complex of a least coordinating solvent and a least coordinating anion

Propagation and Synchronization of Potential Oscillations in Multiple Liquid Membrane Systems

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Tetrakis[3,5-bis(trifluoromethyl)phenyl]borate. Highly Lipophilic Stable Anionic Agent for Solvent-extraction of Cations

Cited by 381 publications

References 17 publications

High spatial resolution measurements in lake sediments with PVC based liquid membrane ion‐selective electrodes

High spatial resolution measurements in lake sediments with PVC based liquid membrane ion‐selective electrodes

Preparation and characterization of Tl(1,2-C2H4Cl2)B(OTeF5)4: a metal complex of a least coordinating solvent and a least coordinating anion

Propagation and Synchronization of Potential Oscillations in Multiple Liquid Membrane Systems

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Preparation and characterization of Tl(1,2-C₂H₄Cl₂)B(OTeF₅)₄: a metal complex of a least coordinating solvent and a least coordinating anion