Tetrazoles. 9. Acid-base properties of 5-substituted tetrazoles

Островский, В. А.; Koldobskii, G. I.; Shirokova, N. P.; Poplavskii, V. S.

doi:10.1007/bf00503349

Cited by 16 publications

(11 citation statements)

References 9 publications

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“…[23] It was found that 4,5-dinitroimidazole and 5-nitrotetrazole, which are strong NH acids (pK a = -0.8 for 5-nitrotetrazole) [24] with electron-withdrawing nitro substituents on the ring, can be readily quaternized with azoles to form energetic azolium-azolate salts.…”

Section: Resultsmentioning

confidence: 99%

Energetic Nitrate, Perchlorate, Azide and Azolate Salts of Hexamethylenetetramine

et al. 2006

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Hexamethylenetetrammonium salts, composed of energetic anions 3,5-dinitropyrazolate, 4,5-dinitroimidazolate, 3,5-dinitro-1,2,4-triazolate, 5-nitrotetrazolate, perchlorate, nitrate and azide, were synthesized and characterized. The structure of N-methyl-hexamethylenetetrammonium 3,5-dinitro-1,2,4-triazolate (6) was confirmed by X-ray analysis. The standard enthalpies of formation for the new salts were cal-

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Section: Resultsmentioning

confidence: 99%

Energetic Nitrate, Perchlorate, Azide and Azolate Salts of Hexamethylenetetramine

et al. 2006

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“…In the vibrational spectra, there are significant shifts and broadening in the infrared spectral bands which are typically assigned to the NH 2 stretching environments. Typically upon N-protonation of one of the ring nitrogen atoms of a high nitrogen heterocycle with weakly basic pendant amino groups, there are blue shifts of the amino stretches typically in the range of 30 -50 cm À1 [13,17,41,55]. Accompanying this shift there is the appearance of a broad absorbance ranging from 2600 -2900 cm À1 that is strong evidence of À N À H À N hydrogen bonding resulting from interactions in the solid state.…”

Section: Methodsmentioning

confidence: 99%

Experimental and Theoretical Study of 1,5‐Diamino‐4‐H‐1,2,3,4‐Tetrazolium Perchlorate

Drake

Hawkins

Boatz

et al. 2005

Propellants Explo Pyrotec

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“…Ein Nitrosubstituent verbessert die Sauerstoffbilanz energetischer Salze, sodass letztlich höhere Verbrennungswärmen erzielt und Detonationsvorgänge möglich werden. Die Sauerstoffkoeffizienten α 44 der Salze liegen zwischen 0.18 und 0.33 und somit im Bereich bekannter energetischer Verbindungen 45. Unter allen Azoliumazolaten hatte 1‐Methyl‐3‐azido‐1,2,4‐triazolium‐5‐nitrotetrazolat ( 43 d ) die höchste Bildungswärme.…”

Section: Triazoliumsalzeunclassified

Olive oil composition as a function of nitrogen, phosphorus and potassium plant nutrition

et al. 2009

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BACKGROUND: Macronutrients play fundamental roles in processes affecting olive oil productivity and are expected to influence oil composition. A necessary step in optimal nutrient application management for olives is an understanding of the relationship between olive tree nutritional status and oil quality parameters. We studied the independent effects of N, P and K concentrations in irrigation solution on the oil quality of 'Barnea' olives by applying a wide range of macronutrient concentrations under highly controlled conditions.

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Tetrazoles. 9. Acid-base properties of 5-substituted tetrazoles

Cited by 16 publications

References 9 publications

Energetic Nitrate, Perchlorate, Azide and Azolate Salts of Hexamethylenetetramine

Energetic Nitrate, Perchlorate, Azide and Azolate Salts of Hexamethylenetetramine

Experimental and Theoretical Study of 1,5‐Diamino‐4‐H‐1,2,3,4‐Tetrazolium Perchlorate

Olive oil composition as a function of nitrogen, phosphorus and potassium plant nutrition

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