Geometric arrangements of hexagons into six sides of benzenoids are known as coronoid systems. They are organic chemical structures by definition. Hollow coronoids are divided into two types: primitive and catacondensed coronoids. Polycyclic conjugated hydrocarbon is another name for them. Chemical mathematics piques the curiosity of scientists from a variety of disciplines. Graph theory has always played an important role in making chemical structures intelligible and useful. After converting a chemical structure into a graph, many theoretical and investigative studies on structures can be carried out. Among the different parameters of graph theory, the dimension of edge metric is the most recent, unique, and important parameter. Few proposed vertices are picked in this notion, such as all graph edges have unique locations or identifications. Different (edge) metric-based concept for the structure of hollow coronoid were discussed in this study.