The acid-base reactions of the ?-hydroxypiperidinecarboxylic acids

Korolev, B. A.; Stolyarova, L. G.; Смирнов, Л. Д.; Dyumaev, K. M.

doi:10.1007/bf00947375

Cited by 1 publication

(2 citation statements)

References 7 publications

Supporting

Mentioning

Contrasting

Order By: Relevance

“…[24,37] [a] n is the number of experiments from which the data were obtained; the reported uncertainty is the standard deviation of the mean.…”

Section: Acidity Constants Of the Ligandsmentioning

confidence: 99%

“…This deprotonation has been assigned to the carboxylic group. [37] It may be noted that for the carboxylic group in nicotinic acid, pK a1 ഠ 2; [38] as the ortho-phenol group can be expected to produce a significant increase in the acidity (for example, the carboxylic pK a of salicylic acid is ca. 1.2 units lower than that of benzoic acid [38] ), the values obtained for H 3 L appear to be reasonable.…”

Section: Acidity Constants Of the Ligandsmentioning

confidence: 99%

See 1 more Smart Citation

Evaluation of 3,4-Hydroxypyridinecarboxylic Acids as Possible Bidentate Chelating Agents for Aluminium(III): Synthesis and Metal−Ligand Solution Chemistry

Marco

Yokel

Ferlin

et al. 2002

Eur. J. Inorg. Chem.

View full text Add to dashboard Cite

In view of a possible application to aluminium(III) chelation therapy, 3-hydroxy-4-pyridinecarboxylic acid (3H4P) and 4-hydroxy-3-pyridinecarboxylic acid (4H3P) were synthesised, and their chemical interactions with the metal ion were investigated in aqueous 0.6 m (Na)Cl at 25°C by means of potentiometric titrations. Only mononuclear complexes of the type AlL l H h (l = 1, 2 and 3; h = 0, 1, ..., l) were formed. The qualitative and quantitative results obtained were confirmed by UV spectrophotometry and 1 H NMR spectroscopy. The efficiencies of the ligands to chelate aluminium(III) were evalu-

show abstract

“…[24,37] [a] n is the number of experiments from which the data were obtained; the reported uncertainty is the standard deviation of the mean.…”

Section: Acidity Constants Of the Ligandsmentioning

confidence: 99%

Section: Acidity Constants Of the Ligandsmentioning

confidence: 99%