The Addition of Ethanethiolic Acid to 3β-Acetoxy-5,16-pregnadien-20-one

Dodson, R. M.; Sollman, Paul B.; Deason, James R.

doi:10.1021/jo01017a071

J. Org. Chem.

1965

DOI: 10.1021/jo01017a071

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The Addition of Ethanethiolic Acid to 3β-Acetoxy-5,16-pregnadien-20-one

R. M. Dodson¹,

Paul B. Sollman²,

James R. Deason³

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1969

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Cited by 3 publications

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Photoaddition of Acetylcyclohexane and Ethanol

Rubin

1969

Israel Journal of Chemistry

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1‐Acetylcyclohexene undergoes photoaddition with ethanol to give, initially, cis‐ and trans‐2‐ethoxy‐1‐acetylcyclohexane. The thermodynamically less stable cis isomer is the major product. No products resulting from photochemical hydrogen atom abstraction from ethanol by photoexcited ketone were observed in contrast to the results obtained with an acetylcyclopentene derivative. The initially formed adducts undergo a further photochemical reaction, intramolecular hydrogen atom abstraction, to give derivatives of octahydrobenzofuran. Quantum yields for disappearance of acetylcyclohexene in ethanol were 0.04 at 2537Å and 0.25 at 3130Å.

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Photoaddition of Acetylcyclohexane and Ethanol

Rubin

1969

Israel Journal of Chemistry

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Transformed steroids

et al. 1970

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Transformed steroids

Akhrem

Kuznetsova

1969

Russ Chem Bull

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The Addition of Ethanethiolic Acid to 3β-Acetoxy-5,16-pregnadien-20-one

Cited by 3 publications

References 6 publications

Photoaddition of Acetylcyclohexane and Ethanol

Photoaddition of Acetylcyclohexane and Ethanol

Transformed steroids

Transformed steroids

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