Modern Arene Chemistry 2002
DOI: 10.1002/3527601767.ch7
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The ADIMET Reaction: Synthesis and Properties of Poly(dialkyl para phenyleneethynylene)s

Abstract: A mixture of molybdenum hexacarbonyl and 4-chlorophenol is effective in performing alkyne metathesis of dipropynylated dialkylbenzenes. Alkyne metathesis of these precursors leads to the clean formation of dialkyl poly( paraphenyleneethynylene)s (PPEs) in high yield and with high molecular weights. This facile yet effective access to the PPEs has allowed study of their spectroscopic, structural, and thermal properties. While PPEs have been made before, the dialkyl-PPEs turned out to have particularly interesti… Show more

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Cited by 5 publications
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References 49 publications
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