1987
DOI: 10.1016/s0584-8539(87)80059-4
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The adsorption and reaction of methanol on oxidized copper(111) studied by Fourier transform reflection-absorption infrared spectroscopy

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Cited by 110 publications
(104 citation statements)
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“…The weak feature at 2123 cm-I, which also appears in the spectrum of methanold4 at 2128 cm-I, is attributed to the combination band v(C0) + d,(CD3), in accordance with the corresponding assignment on Cu{ 11 l}. 34 The assignment of the remaining band at 2185 cm-' determines the identity of the contentious band in the methoxy RAIR spectrum. It is fairly broad (fwhm 20 cm-I) compared to the other bands (fwhm -10 cm-I), suggesting that there is more than one component involved.…”
Section: Vibrational Structure Of Methoxy On Ag{lll)supporting
confidence: 63%
“…The weak feature at 2123 cm-I, which also appears in the spectrum of methanold4 at 2128 cm-I, is attributed to the combination band v(C0) + d,(CD3), in accordance with the corresponding assignment on Cu{ 11 l}. 34 The assignment of the remaining band at 2185 cm-' determines the identity of the contentious band in the methoxy RAIR spectrum. It is fairly broad (fwhm 20 cm-I) compared to the other bands (fwhm -10 cm-I), suggesting that there is more than one component involved.…”
Section: Vibrational Structure Of Methoxy On Ag{lll)supporting
confidence: 63%
“…6 These results compare well with RAIRS spectra on Ag(111) 11 and on Cu(111). 22 Quasi-relativistic DFT calculations on Pt(111) pointed to identical results. 5 Hybrid HF/DFT methods were performed for methoxide adsorbed on a less compact surface, Al(100), indicating a preference toward adsorption on 2-fold bridge sites.…”
Section: Introductionmentioning
confidence: 75%
“…4,11,22,24,31 The methyl deformation region is of no use to this matter, since the modes are too weak to be observed. This has also been the case in other RAIRS studies.…”
Section: Ch 3 O (Ads) + H (Ads) 98mentioning
confidence: 99%
“…As for comparison, we can note that the C-O stretching of methoxy groups on ␥-Al 2 O 3 is found at 1095 cm −1 [28], and those on ZnO and ZnO-based systems [29] at 1060 cm −1 . Methoxy groups on CuO are reported to be very labile, whose C-O stretching is found at 1070 cm −1 , and finally, those on Cu(1 1 1) [30] absorb at 1036 cm −1 . The complex weak band centered in the region 1470-1440 cm −1 (maximum at 1458 cm −1 ), and the component at 1190 cm −1 are most likely due to the bending and rocking modes, respectively, of the CH 3 of the methoxy groups.…”
Section: Ir Study Of Methanol Adsorption and Conversionmentioning
confidence: 99%