The influence of substrate misorientation degree on
the composition and morphology of layers during molecular-beam
epitaxy of InAsxSb1−x solid solutions on the GaAs surface was
studied. The GaAs wafers with orientation (001), which were
miscuted in the [110] direction by 0, 1, 2 and 5◦, were used
as substrates. The growth of heterostructures was performed for
temperatures of 310◦C and 380◦C (lower and upper boundaries
for the temperature range of structurally perfect InAsx Sb1−x films
formation, respectively). The influence of the arsenic molecular
form (As2 or As4) on the composition of layers was studied.
Studies of composition and structural properties were carried
out using high-resolution X-ray diffractometry (HRXRD) and
atomic force microscopy (AFM). It was established that in the
series of misorientation from 0 to 5◦ the arsenic fraction x increases
consecutively with the use of both flux of As2 and flux of
As4 molecules. When the flux of As2 molecules is used, the
fraction x increases insignificantly (in 1.05 times) with a rise of
misorientation degree, but when using As4 molecules, x increases
in 1.75 times. The increase of the growth temperature leads to the
rise of the arsenic fraction in the solid solution. The morphology
of the surface improves during increasing of misorientation degree
at a low growth temperature and degrades at high temperatures.