1979
DOI: 10.1016/0013-4686(79)87019-x
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The anodic characteristics of massive manganese oxide electrode

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Cited by 129 publications
(114 citation statements)
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“…However as opposed to the MnCat, the catalytic activity of b-Mn IV O 2 is exceedingly low. 29 Well-ordered, microcrystalline Mn oxides generally may be largely inactive in water oxidation. 15,61 The prevalence of coordinatively saturated m 3-5 -oxo bonds and the absence of terminal coordination sites for water binding appear to preclude water-oxidation activity in both well ordered colloidal (see ref.…”
Section: Structure-function Relationmentioning
confidence: 99%
“…However as opposed to the MnCat, the catalytic activity of b-Mn IV O 2 is exceedingly low. 29 Well-ordered, microcrystalline Mn oxides generally may be largely inactive in water oxidation. 15,61 The prevalence of coordinatively saturated m 3-5 -oxo bonds and the absence of terminal coordination sites for water binding appear to preclude water-oxidation activity in both well ordered colloidal (see ref.…”
Section: Structure-function Relationmentioning
confidence: 99%
“…Taking early studies of electro-or photon-driven Co and Mn oxide catalysts as point of departure [1][2][3][4][5][6][7][8][9][10][11][12][13][14][15][16], development of nanostructured forms of these oxides featuring very high surface areas have dramatically increased turnover frequencies of O 2 product formation per projected catalyst area [17][18][19]. The need for high turnover frequency per projected area in artificial photosynthesis is based on the requirement that the catalyst should keep up with the incident solar flux in order to minimize wasting of photons.…”
Section: Introductionmentioning
confidence: 99%
“…54 Manganese oxides have also been known to effect electrocatalytic water oxidation for some time. 55,56 Over the last few years, however, there has been a resurgence of interest in these materials, with a new emphasis on mild conditions and improved current densities. In 2010, Gorlin and Jaramillo reported a bifunctional Mn-based catalyst, able to catalyse both water oxidation and its reverse (the ORR) in 0.1 M KOH solution.…”
Section: Electrodeposited Catalysts For Water Oxidation Based On Mangmentioning
confidence: 99%