Unexpectedly, the surface of Mercury is depleted in iron (<2 wt%; Weider et al., 2014) but enriched in volatiles such as sulfur (∼4 wt% on average; Nittler et al., 2011). These unique geochemical characteristics are attributed to element partitioning in melts in a low oxygen fugacity environment (Namur et al., 2016;Vander Kaaden & McCubbin, 2015;Zolotov et al., 2013). Candidate volatile species on Mercury (e.g., MgS and CaS) are unstable in the high temperature (Helbert et al., 2013) and strong radiation surface environment, as evidenced by the widespread and ongoing volatile loss that is forming hollows (Blewett et al., 2011(Blewett et al., , 2018. To support the long-term formation of hollows, surface and subsurface volatiles must have been chronically replenished by endogenic (e.g., sequestered volcanic gasses) and/or exogenic (e.g., impact excavation of deeper volatile-rich materials) processes (Blewett et al., 2013;. However, the connection(s) between surface and interior volatiles (e.g., S) is not clear.A consensus has recently emerged that carbon in the form of graphite is a major darkening phase on Mercury (Klima et al., 2018;Murchie et al., 2015;Peplowski et al., 2016). Typical opaque minerals on the other terrestrial bodies (e.g., ilmenites) are not abundant on Mercury as evidenced by the low Fe and Ti concentrations (Murchie et al., 2015). On the contrary, carbon was recently implied to be present in various terrains on Mercury (Peplowski et al., 2016). When resolved at sufficient spatial resolutions, low-reflectance materials