BackgroundCoffee is a natural drink with important properties for the human body and mind, capable of delivering energy and strong emotions, thus being appreciated since ancient times. The qualitative and quantitative assessment of the coffee properties is normally performed by trained panelists, however relying on standardized questionnaires, with possible biases arising. In the present study, for the first time in the scientific literature, we applied a technology‐based approach, based on the use of wearable sensors, to study the implicit emotional responses of a small cohort of experienced coffee judges, thus taking this chance to assess the approach feasibility in such a scenario. The merging of different technologies for capturing biomedical signals, including electrocardiogram (ECG), galvanic skin response (GSR) and electroencephalogram (EEG) was therefore adopted, to retrieve results in terms of the relationships between implicit (i.e., psychophysiological) and explicit (i.e., derived from questionnaires) measurements.ResultsSignificant correlations were obtained between biomedical signals and data from the questionnaires within all the sensory domains (olfaction, vision, taste) investigated, particularly concerning autonomic‐related features.ConclusionsThe results obtained confirmed the viability of this new approach in the psychophysical and emotional assessment in coffee tasting judges, paving the way for a new perspective into the universe of coffee quality assessment panels, eventually transferable to broader scale investigations, somewhat dealing with consumer satisfaction and neuromarketing at large.This article is protected by copyright. All rights reserved.