Superhydrophobic surfaces have drawn attention from scientists and engineers because of their extreme water repellency. More interestingly, these surfaces have also demonstrated an infinite influence on civil engineering materials. In this feature article, the history of wettability theory is described firstly. The approaches to construct hierarchical micro/nanostructures such as chemical vapor deposition (CVD), electrochemical, etching, and flame synthesis methods are introduced. Then, the advantages and limitations of each method are discussed. Furthermore, the recent progress of superhydrophobicity applied on civil engineering materials and its applications are summarized. Finally, the obstacles and prospects of superhydrophobic civil engineering materials are stated and expected. This review should be of interest to scientists and civil engineers who are interested in superhydrophobic surfaces and novel civil engineering materials.