The Applications of Reticular Framework Materials

doi:10.1002/9783527821099.ch12

Cited by 2 publications

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“…Coordination polymers (CPs) were created by linking together many themes of carboxylic acids, metal salts, and occasionally supplementary organic ligands. − For prospective uses such as sensors, catalysts, medication delivery, and gas storage, CPs have recently advanced. − The variety of architectures and topologies of CPs are also of great interest. However, choosing optimal donor atom ligands as well as reaction circumstances like the right solvent system pose significant challenges to the intelligent and specialized design of CPs .…”

Section: Introductionmentioning

confidence: 99%

Sensitivity to NH₃ Vapor: Synthesis and Characterization of Five New Coordination Polymers Based on 2,2-Dimethylglutaric Acid and Bis(triazole)-Derived Ligands

Köse Yaman,

Demir,

Demir

et al. 2024

ACS Omega

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Five new coordination polymers (CPs) were obtained as a result of hydrothermal reactions of 2,2-dimethylglutaric acid (H 2 dmg) and 1,4-bis(1H-1,2,4-triazol-1-ylmethyl)benzene (pbtx)/1,2-bis(1H-1,2,4-triazol-1-ylmethyl)benzene (obtx) ligands with some metal ions [Co(μ-dmg) 5). All of the compounds were characterized by elemental analysis, FT-IR spectroscopy, single-crystal X-ray diffraction, powder X-ray diffraction, and thermal analysis techniques. The single-crystal X-ray studies show that all compounds exhibit 2D layer structures. To examine the ammonia sensing properties of five new coordination complexes (1−5), the absorption and emission spectra of CPs embedded in ethyl cellulose thin films were measured by exposure to different concentrations of ammonia (NH 3 ) vapor. The [Co 2 (μ-dmg) 2 (μ-pbtx) 2 ] n (4)-based sensor agent was found to show promising sensor properties in detecting NH 3 vapor.

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Section: Introductionmentioning

confidence: 99%

Sensitivity to NH₃ Vapor: Synthesis and Characterization of Five New Coordination Polymers Based on 2,2-Dimethylglutaric Acid and Bis(triazole)-Derived Ligands

Köse Yaman,

Demir,

Demir

et al. 2024

ACS Omega

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Formation of a mixed-valence Cu(i)/Cu(ii) metal–organic framework with the full light spectrum and high selectivity of CO₂ photoreduction into CH₄

Gao

Zhang

et al. 2020

Chem. Sci.

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The Applications of Reticular Framework Materials

Cited by 2 publications

References 83 publications

Sensitivity to NH₃ Vapor: Synthesis and Characterization of Five New Coordination Polymers Based on 2,2-Dimethylglutaric Acid and Bis(triazole)-Derived Ligands

Sensitivity to NH₃ Vapor: Synthesis and Characterization of Five New Coordination Polymers Based on 2,2-Dimethylglutaric Acid and Bis(triazole)-Derived Ligands

Formation of a mixed-valence Cu(i)/Cu(ii) metal–organic framework with the full light spectrum and high selectivity of CO₂ photoreduction into CH₄

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The Applications of Reticular Framework Materials

Cited by 2 publications

References 83 publications

Sensitivity to NH3 Vapor: Synthesis and Characterization of Five New Coordination Polymers Based on 2,2-Dimethylglutaric Acid and Bis(triazole)-Derived Ligands

Sensitivity to NH3 Vapor: Synthesis and Characterization of Five New Coordination Polymers Based on 2,2-Dimethylglutaric Acid and Bis(triazole)-Derived Ligands

Formation of a mixed-valence Cu(i)/Cu(ii) metal–organic framework with the full light spectrum and high selectivity of CO2 photoreduction into CH4

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Sensitivity to NH₃ Vapor: Synthesis and Characterization of Five New Coordination Polymers Based on 2,2-Dimethylglutaric Acid and Bis(triazole)-Derived Ligands

Sensitivity to NH₃ Vapor: Synthesis and Characterization of Five New Coordination Polymers Based on 2,2-Dimethylglutaric Acid and Bis(triazole)-Derived Ligands

Formation of a mixed-valence Cu(i)/Cu(ii) metal–organic framework with the full light spectrum and high selectivity of CO₂ photoreduction into CH₄