Cenozoic volcanic rocks were recently discovered during full-coring kilometer-scale major scientific drilling in the Xisha Islands, northwestern South China Sea. A systematic mineralogical study of these samples was performed for this paper. The results show that the volcanic rock samples are basaltic pyroclastic. The major elements demonstrate that the clinopyroxenes are diopside and fassaite, which contain high Al 2 O 3 (5.33-11.2 wt. %), TiO 2 (2.13-4.78 wt. %) and wt. %). Clinopyroxenes have high REE abundances (104-215 ppm) and are strongly enriched in LREE (LREE/HREE = 3.56-5.14, La/Yb N = 2.61-5.1). Large-ion lithophile elements show depleted characteristics. Nb/Ta shows obvious fractionation features: Nb is lightly enriched, relative to primitive mantle, but Ta is heavily depleted, relative to primitive mantle. The parental magma of the basaltic pyroclastic rocks belongs to a silica-undersaturated alkaline series, characterized by a high temperature, low pressure, and low oxygen fugacity. The Al IV content increases with decreasing Si concentration. The Si-unsaturated state causes Si-Al isomorphic replacement during the formation of clinopyroxene. The electric charge imbalance caused by the replacement of Si by Al is mainly compensated by Fe 3+ . The clinopyroxene discrimination diagrams show that the parental magma formed in an intraplate tectonic setting environment.The mineral composition of igneous rocks depends on the chemical composition and crystallization environment of magma. Changes in mineral composition and structure are direct evidence of changes in the diagenetic environment and material composition. Therefore, the characteristics of mineral composition can be used to explore mineral petrogenesis and the magma evolution mechanism [18]. Clinopyroxene is one of the main rock-forming minerals of mafic-ultramafic rocks and plays a major role in the generation and subsequent differentiation of magma [16,[19][20][21][22][23][24]. Clinopyroxene composition mainly depends on primary magma characteristics, the crystallization environment, and the tectonic setting of magmatism [25][26][27][28][29][30][31][32]. Relative to other minerals in mafic-ultramafic rocks, clinopyroxene is considered to be the main carrier for most trace elements and holds a unique further record of magma history [33,34]. The mineral chemistry of relict clinopyroxene in igneous rocks can reflect the characteristics of the primary magma well and has been widely used to study the nature of the original magma and complicated processes that have affected the lithospheric mantle [21,[35][36][37][38][39][40][41][42]. Furthermore, clinopyroxenes in altered basalts are of interest, because they often survive in a relatively pristine form, after the matrix and other minerals have been converted to secondary minerals. The major-and minor-element geochemistry of clinopyroxene is varied and provides a filtered view of the composition of the magma from which the clinopyroxene crystallized, lending it the potential to provide insight into t...