The Behavior of the Deformation Vibration of NH3 in Semi-Organic Crystals under High Pressure Studied by Raman Spectroscopy

Abstract

Single-crystal samples of the semi-organic compounds mono-L-alaninium nitrate and monoglycine nitrate have been studied by Raman spectroscopy in a diamond-anvil cell up to 5.5 GPa, in order to observe the behavior of the deformation mode of NH 3 units. It was observed for these semi-organic crystals that increasing pressure produces a decrease in the wavenumber of the band associated with the deformation vibration, differently from most of the modes. Comparatively, mono-L-alaninium has a higher dν/dP than monoglycine nitrate, for the band associated with the deformation vibration. The anomalous behavior is explained in terms of the effect of high pressure in the short and linear intermolecular hydrogen bonds.

The Behavior of NH3+ Torsional Vibration in Amino Acids: A Raman Spectroscopic Study

“…Eventually, these contributions can be inferred from the Raman spectrum with bands associated with modes of low energy. On the other hand, from bands associated with vibrations belonging to CO 2 and NH 3 groups, one can discover various aspects from conformation of the molecules in the unit cell and the effect of thermodynamics parameters on the hydrogen bonds [18].…”