This study examined an effective way of measuring the evacuation performance in buildings, which are applied to a double skin facade through an evaluation of the escape safety. Buildings with a double skin facade appeared to have a faster combustion expansion speed for the upper floor if a fire occurs. Moreover, a double skin facade is more difficult to escape safely than a general building construction because of the limited design standards. Accordingly, this study suggested virtual modeling including single emergency stairs and alarm systems considering the risk in each structure of buildings. These results showed that box-type double skin, corridor access type, shaft-box type, and multistory facade systems showed a 26.4%, 29.1%, 23.4%, and 26.3% increase in evacuation performance, respectively, as well as securing the safety of occupants..