Practical application of the electrochemical
method for enhancing coalbed methane (CBM) extraction is limited due
to the insufficiency of in-depth experimental and theoretical research.
Therefore, H2SO4, Na2SO4, and NaOH electrolytes with different pH values were selected to
electrochemically modify lean coals and their CH4 adsorption
and desorption behaviors were tested. The experimental results showed
that the amount of CH4 adsorption decreased after modification
using H2SO4 and Na2SO4 electrolytes, and increased after electrochemical modification using
the NaOH electrolyte. The ratio of CH4 desorption increased
from 83.20 to 90.10 and 87.84%, respectively, after electrochemical
modification using H2SO4 and Na2SO4 electrolytes, and decreased to 81.71% after electrochemical
modification using the NaOH electrolyte. The pore volume and average
pore size increased, and the specific surface area decreased with
the decrease of electrolyte pH. Lower pH electrolytes perform better
and the mechanism was analyzed by the change of surface energy, surface
groups, and pore structures. The work will provide a basis for the
reasonable selection of electrolyte pH when using in situ electrochemical
methods for enhancing CBM extraction.