The Catalyst-free Addition of Dialkyl Phosphites on the Triple Bond of Alkyl Phenylpropiolates Under Microwave Conditions

Bálint, Erika; Takacs, J. M.; Bálint, Mária; Keglevich, György

doi:10.2174/2211544704666150303232225

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Reactions Taking Place More Efficiently Under Mw Conditions1

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Cited by 7 publications

(1 citation statement)

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“…MW addition was useful to enhance the addition of dialkyl phosphites, ethyl phenyl‐ H ‐phosphinate and diphenylphosphine oxide to the more reactive double‐bond of N ‐phenyl and N ‐methylmaleimide, as well as maleic anhydride . The addition of two equivalents of >P(O)H species to dimethyl acetylenedicarboxylate and analogous derivatives was also studied …”

Section: Reactions Taking Place More Efficiently Under Mw Conditionsmentioning

confidence: 99%

The Impact of Microwaves on Organophosphorus Chemistry

Keglevich

2018

The Chemical Record

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A personal account on the pioneering results on microwave (MW)-assisted organophosphorus syntheses obtained in the last decade is presented. The broad spectrum of the reactions studied exemplifies the advantages of the MW technique as a green tool regarding efficiency and the simplification of catalyst systems. Theoretical calculations for a few typical models helped us to explore the scope and limitations of the application of MW irradiation.

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Section: Reactions Taking Place More Efficiently Under Mw Conditionsmentioning

confidence: 99%

The Impact of Microwaves on Organophosphorus Chemistry

Keglevich

2018

The Chemical Record

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Stereoselective Thermal Addition of R_P and/or S_P‐Menthyl‐Deriving Secondary Phosphine Oxides to Active Alkynes, the Mechanism, Stereochemistry and Generation of P,C‐Chirogenic Bis‐Phosphine Derivatives

Yan

Zheng

et al. 2020

Asian J Org Chem

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The Use of MW in Organophosphorus Chemistry

Keglevich

Bálint²,

Kiss

2016

SpringerBriefs in Molecular Science

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The third chapter summarizes a special field, the application of the microwave (MW) technique in the synthesis of organophosphorus compounds. On the one hand, reactions are shown that are otherwise rather reluctant on traditional thermal heating. On the other hand, reactions are discussed, which, became more efficient (shorter reaction times and higher yields) on MW irradiation. Finally, the simplification of catalytic systems under MW conditions are surveyed.

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The Catalyst-free Addition of Dialkyl Phosphites on the Triple Bond of Alkyl Phenylpropiolates Under Microwave Conditions

Cited by 7 publications

References 40 publications

The Impact of Microwaves on Organophosphorus Chemistry

The Impact of Microwaves on Organophosphorus Chemistry

Stereoselective Thermal Addition of R_P and/or S_P‐Menthyl‐Deriving Secondary Phosphine Oxides to Active Alkynes, the Mechanism, Stereochemistry and Generation of P,C‐Chirogenic Bis‐Phosphine Derivatives

The Use of MW in Organophosphorus Chemistry

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The Catalyst-free Addition of Dialkyl Phosphites on the Triple Bond of Alkyl Phenylpropiolates Under Microwave Conditions

Cited by 7 publications

References 40 publications

The Impact of Microwaves on Organophosphorus Chemistry

The Impact of Microwaves on Organophosphorus Chemistry

Stereoselective Thermal Addition of RP and/or SP‐Menthyl‐Deriving Secondary Phosphine Oxides to Active Alkynes, the Mechanism, Stereochemistry and Generation of P,C‐Chirogenic Bis‐Phosphine Derivatives

The Use of MW in Organophosphorus Chemistry

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Product

Resources

About

Stereoselective Thermal Addition of R_P and/or S_P‐Menthyl‐Deriving Secondary Phosphine Oxides to Active Alkynes, the Mechanism, Stereochemistry and Generation of P,C‐Chirogenic Bis‐Phosphine Derivatives