2005
DOI: 10.1016/j.apcata.2005.07.023
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The catalytic active sites in partially reduced MoO3 for the hydroisomerization of 1-pentene and n-pentane

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Cited by 28 publications
(6 citation statements)
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“…Besides, no other metal is found, especially for the contaminative Fe in the as-prepared WO 3 and MoO 3 films (Figure S6). From the core level XPS spectra of Fe 2p, W 4f, and Mo 3d in Figure S7, dominant states of Fe 3+ , W 6+ , and Mo 6+ can be recognized, according to the BE peaks at 710.9 eV (Fe 2p 3/2 ), 35.6 eV (W 4f 7/2 ), and 232.6 eV (Mo 3d 5/2 ), respectively.…”
Section: Resultsmentioning
confidence: 99%
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“…Besides, no other metal is found, especially for the contaminative Fe in the as-prepared WO 3 and MoO 3 films (Figure S6). From the core level XPS spectra of Fe 2p, W 4f, and Mo 3d in Figure S7, dominant states of Fe 3+ , W 6+ , and Mo 6+ can be recognized, according to the BE peaks at 710.9 eV (Fe 2p 3/2 ), 35.6 eV (W 4f 7/2 ), and 232.6 eV (Mo 3d 5/2 ), respectively.…”
Section: Resultsmentioning
confidence: 99%
“…Figure 2a S6). From the core level XPS spectra of Fe 2p, W 4f, and Mo 3d in Figure S7, dominant states of Fe 3+ , W 6+ , and Mo 6+ can be recognized, according to the BE peaks at 710.9 eV (Fe 2p 3/2 ), 44 35.6 eV (W 4f 7/2 ), 45 and 232.6 eV (Mo 3d 5/2 ), 46 respectively. The core level XPS spectra of Pd 3d in metal-oxide/Pd catalysts are displayed in Figure 2c together with those in metallic Pd, Pd-250, Pd-350, and Pd-450.…”
Section: Resultsmentioning
confidence: 99%
“…However, after the milling process more signals were recorded accounting for the presence of other elements such as Mg, Si, Ca, Fe and Cu and with an increased oxygen content ( Figure 1E). Mo 5+ and Mo 6+ [15,16] as a result of an oxidative process occurring during the ball-milling. This is also supported by the higher content of oxygen as depicted in Figure 1A and 2A.…”
Section: Resultsmentioning
confidence: 99%
“…W 4f could be divided into W 4f 7/2 peaks with a binding energy of 35.6 eV and W 4f 5/2 peaks with a binding energy of 37.40 eV, both of which corresponded to WO 3 . 49 This means that W always existed in the catalyst in the form of WO 3 , independent of calcination temperature.…”
Section: Energy and Fuelsmentioning
confidence: 99%