The cathodic reduction of nitrous acid in the second reduction step in high acid solutions by the potential step method (formation of HNO)

Heckner, H. N.

doi:10.1016/s0022-0728(77)80500-7

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Cited by 3 publications

References 19 publications

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Nitrogen Oxides and Oxyanions

Inzelt

Horányi

2006

Encyclopedia of Electrochemistry

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The sections in this article are Fundamentals Practical and Theoretical Importance of the Field Electrochemical Transformations of NO 2 − , NO 3 − ( HNO 2 , HNO 3 ) Electrochemistry and Electrochemical Detection of NO Reactions of N 2 O Acknowledgment

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Nitrogen Oxides and Oxyanions

Inzelt

Horányi

2006

Encyclopedia of Electrochemistry

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ChemInform Abstract: THE CATHODIC REDUCTION OF NITROUS ACID IN THE SECOND REDUCTION STEP IN HIGHLY ACIDIC SOLUTIONS BY THE POTENTIAL STEP METHOD (FORMATION OF HNO)

HECKNER¹

1977

Chemischer Informationsdienst

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Oxidation of benzyl alcohols by nitrous and nitric acids in strong sulfuric acid media

Ross

Hum

et al. 1986

Int J of Chemical Kinetics

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We have studied the oxidation of benzyl alcohols by nitrous and nitric acid in sulfuric acid media. The oxidation by nitrous acid is rapid and has an activation energy of 10.6 -t 0.8 kcal mol-'. A Hammett plot of logkp vs. u -is linear with a p value of -1.4. The oxidation by nitric acid in sulfuric acid media is autocatalytic. From the kinetic and product analyses, it is concluded that a common oxidant, the nitrosonium ion is involved when either nitrous or nitric acid is used. A mechanism is proposed which involves the abstraction of hydride from the alcohols as the rate determining step. It is demonstrated that the autoxidation of the alcohols is catalyzed by nitrous acid or nitric oxide.

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The cathodic reduction of nitrous acid in the second reduction step in high acid solutions by the potential step method (formation of HNO)

Cited by 3 publications

References 19 publications

Nitrogen Oxides and Oxyanions

Nitrogen Oxides and Oxyanions

ChemInform Abstract: THE CATHODIC REDUCTION OF NITROUS ACID IN THE SECOND REDUCTION STEP IN HIGHLY ACIDIC SOLUTIONS BY THE POTENTIAL STEP METHOD (FORMATION OF HNO)

Oxidation of benzyl alcohols by nitrous and nitric acids in strong sulfuric acid media

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