The chain structure ofcatena-poly[[(2-tert-butyltetrazole-κN4)copper(II)]-di-μ-chloro]

Lyakhov, Alexander S.; Гапоник, П. Н.; Degtyarik, Mikhail M.; Ivashkevich, Ludmila S.

doi:10.1107/s1600536802023085

Cited by 16 publications

(13 citation statements)

References 5 publications

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“…Earlier studies reported that several tetrazole derivatives possess diverse pharmacological properties (Juby et al, 1968(Juby et al, , 1982. However, crystallographic studies of only a few complexes of monosubstituted tetrazole derivatives have been reported (van den Heuvel et al, 1983;Lyakhov et al, 2003). Here, we report the synthesis and structure of the title novel tetrazole thioether, (I).…”

Section: Commentmentioning

confidence: 84%

trans-5,5′-[(2-Butene-1,4-diyl)dithio]bis(1-phenyl-1,2,3,4-tetrazole)

2004

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Section: Commentmentioning

confidence: 84%

trans-5,5′-[(2-Butene-1,4-diyl)dithio]bis(1-phenyl-1,2,3,4-tetrazole)

2004

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“…217,218 As the substituent bulk increases (R = Pr, CH 2 =CHCH 2 ), both tetrazole ligands become bridging and are coordinated by the N(4) and N(1) atoms (structure 130). 219 Note that complexes 128 ± 130 are the first examples of layered polymeric structures formed by N-substituted tetrazoles through two nitrogen atoms of the heterocycle. The complexes CuLCl 2 and Cu 3 L 4 Cl 6 are polymeric chains 131 and 132, respectively, formed owing to the bridging coordination of chlorine atoms; 220 ± 222 in 132, the neighbouring copper atoms are additionally linked by the tetrazole ring [N(3), N(4) atoms]; hence, a half of the tetrazole ligands in the structure are bridging.…”

Section: Metal Derivatives Of Neutral N-substituted Tetrazolesmentioning

confidence: 99%

Metal derivatives of tetrazoles

Гапоник¹,

2006

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Published data on the synthesis, structure, properties Published data on the synthesis, structure, properties and applications of metal derivatives of tetrazoles are generalised and applications of metal derivatives of tetrazoles are generalised and described systematically. Compounds based on the anionic and described systematically. Compounds based on the anionic and neutral tetrazole forms, and neutral tetrazole forms, C C-and -and N N-mono-and -mono-and C C, ,N N-disubsti--disubstituted tetrazoles are considered. The bibliography includes 464 tuted tetrazoles are considered. The bibliography includes 464 references references. . ReceivedDepending on the reaction conditions, meta-and para-5,5 Hphenyleneditetrazoles 25 react with Cd, Zn and Mn(II) salts to give essentially different, as regards both composition and structure, complexes 26, 27, 44 28, 45 29. 46 The structures of compounds 26 ± 29 were determined by X-ray diffraction. Compounds 26 ± 28 in which the doubly charged anions derived from tetrazole 25 function as bridges are two-and three-dimensional coordination polymers. Conversely, compound 29 is a mononuclear aqua complex containing no metal ± tetrazole coordination bond. In the structure of complex 28, one-dimensional channels were found which occupy up to 35% of the void volume and encapsulate tetrameric cyclic water clusters and DMF molecules. On heating to 150 8C, water and DMF are removed from the channels, which accounts for the interest of researchers in this type of compound for the preparation of inclusion compounds and sorbents. A coordination polymer with a composition similar to complex K + 7

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“…A series of¯exible or rigid chain-linked dithioethers containing N-heterocyclic moieties have been synthesized and investigated (Sharma et al, 1999;Constable et al, 2002;Bu et al, 2003;Hong et al, 2000;. Earlier studies have shown that several tetrazole derivatives possess diverse pharmacological properties (Juby et al, 1968(Juby et al, , 1982, but only a few metal complexes of monosubstituted tetrazole derivatives are known (van den Heuvel et al, 1983;Lyakhov et al, 2003). We report here the synthesis and structure of a new tetrazole dithioether, namely 1,2-bis(1phenyl-1H-tetrazol-5-ylsulfanyl)ethane, (I).…”

Section: Commentmentioning

confidence: 99%