In this study, pristine palygorskite powders were used as the inhibition materials to suppress the explosion of methane-air premixed gas for the first time. The composition, porosity and pyrolysis characteristics of the powders were tested by X-ray diffraction (XRD), energy dispersive spectrometry (EDS), N 2 adsorption-desorption and Thermogravimetry-differential scanning calorimetry (TG-DSC) techniques. The effects of pristine palygorskite powders concentration on the explosion pressure and the average velocity of flame propagation of the 9.5% methane-air premixed gas were tested by a 20 L spherical explosion system and a 5 L pipeline explosion system. The results indicated the pristine palygorskite powders possess a considerable suppression property on methane explosion. When the mass concentration of pristine palygorskite powders was 0.20 g·L −1 , the max-pressure of methane explosion was decreased by 23.9%. The methane explosion flame propagation velocity was inhibited obviously. Owing to the excellent inhibitory performance and the advantage of low-cost and environmental harmlessness, pristine palygorskite powders are potential new materials for the application on gas explosion suppression.Palygorskite clay is a kind of magnesian-aluminum silicate mineral with chain-layer structure [18][19][20]. China is the largest palygorskite clay origin country in the world. The typical Molecular formula of palygorskite is Mg 5 Si 8 O 20 (OH) 2 (H 2 O)·4H 2 O [21], which contains different metal ions related to different origins place, such as Al 3+ , Fe 3+ , Fe 2+ , etc. In recent years, palygorskite clay has been widely used in industrial fields such as petrochemical industry, environmental protection, food industry, ceramics, insulation materials and plastics [22,23]. In view of its structure, composition and high surface area, palygorskite clay may be feasible for application in the field of gas explosion suppression. However, to the best of our knowledge, there is still no research about the application of palygorskite clay in gas explosion suppression.Herein, pristine palygorskite powders were used as methane explosion suppression material for the first time. Pristine palygorskite powders were characterized by the techniques of XRD, EDS, N 2 adsorption-desorption and TG-DSC. The suppression properties of the pristine palygorskite powders for 9.5% methane-air premixed gas were tested in a 20 L spherical explosion vessel and a 5 L pipeline experimental system. Based on the sample characterization results and explosion parameters, the suppression mechanism of the pristine palygorskite powders on the gas explosion was further explored.
Materials and Methods
MaterialsPristine palygorskite powders, which are gray in color, were obtained from Xuyi, Jiangsu province, China. The samples were dried in a vacuum oven at 50 • C for 2 h, and further ground by an agate mortar. Finally, the pristine palygorskite powders for test were collected through a 200 mesh sieve screen.
CharacterizationX-ray diffraction (XRD) analysis was ca...