The Chemical Bond as a Manifestation of Quantum Mechanical Interference: Theory and Applications of the Interference Energy Analysis Using SCGVB Wave Functions

Chemical Aristocracy: He3 Dication and Analogous Noble-Gas-Exclusive Covalent Compounds

“…This process is a hallmark of bond formation across various chemically bonded systems, as evidenced by a substantial body of research. [56][57][58][59][60][61][62][63][64][65][66][67][68]50 In essence, quantum interference acts to redistribute electronic density, concentrating it more in the bonding region and thereby facilitating the bond formation. This pattern is clearly illustrated in the case of He 3 2+ , as shown in Figure 2C.…”

“…The reduction in kinetic energy caused by interference, denoted as T­[I], is accompanied by an increase in the potential energy (V) caused by this effect with the corresponding quantity labeled as V­[I]. This process is a hallmark of bond formation across various chemically bonded systems, as evidenced by a substantial body of research. − , In essence, quantum interference acts to redistribute electronic density, concentrating it more in the bonding region and thereby facilitating the bond formation. This pattern is clearly illustrated in the case of He 3 2+ , as shown in Figure C.…”